Соколов Editorial Advisory Board Chairman: Eugene A. Vaganov Members: Kirill S. Alexandrov Josef J. Gitelzon Vasily F. Shabanov Andrey G. Degermendzhy Valery L. Mironov Gennady L. Pashkov Vladimir V. Shaidurov Veniamin S. Sokolov Editorial Board: Editor-in-Chief: Mikhail I. Gladyshev Founding Editor: Vladimir I. Kolmakov Managing Editor: Olga F. Alexandrova Executive Editor for Chemistry: Boris N. Kuznetsov CONTENTS / СОДЕРЖАНИЕ Nadezhda M. Mikova, Nikolai V. Chesnokov and Boris N. Kuznetsov Study of High Porous Carbons Prepared by the Alkaline Activation of Anthracites – 3 – Valeri E. Tarabanko, Nikolay V. Tarabanko, Anatoly M. Zhyzhaev and Nataliya V. Koropachinskaya A Novel Vanadium Catalyst for Oxidation of Hydrogen Chloride with Dioxygen – 11 – Boris N. Kuznetsov, Svetlana A. Kuznetsova, Vladimir G. Danilov and Olga V. Yatsenkova Abies Wood Delignification by Acetic Acid – Hydrogen Peroxide Mixture under the Action of TiO2 Catalysts and UV Irradiation – 19 – Л. <...> Федоров Строение нового октаэдрического кластерного комплекса рения – [цис-Ca(OPPh3 )4 (H2 O)2 ][{Re6 (μ3 -S)6 – 81 – (μ3 -Br)2 }Br6 ]•2CH3 CN Journal of Siberian Federal University. <...> Chemistry 1 (2009 2) 3-10 ~ ~ ~ УДК 553.93:66.094.7 Study of High Porous Carbons Prepared by the Alkaline Activation of Anthracites Nadezhda M. Mikovaa , Nikolai V. Chesnokova,b and Boris N. Kuznetsova,b 42 K.Marx st., Krasnoyarsk, 660049 Russia b * a Institute of Chemistry and Chemical Technology SB RAS, Siberian Federal University, 79 Svobodny, Krasnoyarsk, 660041 Russia 1 Received 02.03.2009, received in revised form 10.03.2009, accepted 25.03.2009 The influence of alkaline activation on the development of anthracite porous structure under the variation of different factors: anthracite and metal hydroxide origin, their mass ratio in a mixture, activation temperature and duration has been studied. <...> The highest development of anthracite surface area was reached with mass ratio of anthracite/alkali 1:5-7 and the final heating temperature of 800 °С. <...> Under these conditions the maximum value of surface area of carbon material was <...>
Журнал_Сибирского_федерального_университета._Сер._Химия_№1_2009.pdf
Журнал Сибирского федерального университета
Journal of Siberian Federal University
Химия
Chemistry
Редакционный совет
академик РАН Е.А.Ваганов
академик РАН К.С.Александров
академик РАН И.И.Гительзон
академик РАН В.Ф.Шабанов
чл.-к. РАН, д-р физ.-мат.наук
А.Г.Дегерменджи
чл.-к. РАН, д-р физ.-мат. наук
В.Л.Миронов
чл.-к. РАН, д-р техн. наук
Г.Л.Пашков
чл.-к. РАН, д-р физ.-мат. наук
В.В.Шайдуров
чл.-к. РАО, д-р физ.-мат. наук
В.С. Соколов
Editorial Advisory Board
Chairman:
Eugene A. Vaganov
Members:
Kirill S. Alexandrov
Josef J. Gitelzon
Vasily F. Shabanov
Andrey G. Degermendzhy
Valery L. Mironov
Gennady L. Pashkov
Vladimir V. Shaidurov
Veniamin S. Sokolov
Editorial Board:
Editor-in-Chief:
Mikhail I. Gladyshev
Founding Editor:
Vladimir I. Kolmakov
Managing Editor:
Olga F. Alexandrova
Executive Editor for Chemistry:
Boris N. Kuznetsov
CONTENTS / СОДЕРЖАНИЕ
Nadezhda M. Mikova, Nikolai V. Chesnokov
and Boris N. Kuznetsov
Study of High Porous Carbons Prepared by the Alkaline Activation
of Anthracites
– 3 –
Valeri E. Tarabanko, Nikolay V. Tarabanko,
Anatoly M. Zhyzhaev and Nataliya V. Koropachinskaya
A Novel Vanadium Catalyst for Oxidation of Hydrogen Chloride
with Dioxygen
– 11 –
Boris N. Kuznetsov, Svetlana A. Kuznetsova,
Vladimir G. Danilov and Olga V. Yatsenkova
Abies Wood Delignification by Acetic Acid – Hydrogen Peroxide
Mixture under the Action of TiO2
Catalysts and UV
Irradiation
– 19 –
Л.Н.Исаева, Ю.В.Тамаркина, Д.В.Бован,
В.А.Кучеренко
Адсорбция фенола активными углями, полученными
термолизом бурого угля с гидроксидом калия
– 25 –
Г.А. Колягин, В.Л. Корниенко
Электровосстановление кислорода до пероксида водорода
в газодиффузионных электродах в кислых растворах
– 33 –
Â.Â. Сурсякова, Ñ.Í. Êàëÿêèí, Ã.Â. Бурмакина,
А.И. Рубайло
Использование внутреннего стандарта при определении
анионов методом капиллярного электрофореза с косвенным
спектрофотометрическим детектированием
– 42 –
Редактор И.А. Вейсиг Корректор Т.Е. Бастрыгина
Компьютерная верстка И.В. Гревцовой
Подписано в печать 25.03.2009 г. Формат 84х108/16. Усл. печ. л. 7,3.
Уч.-изд. л. 7,0. Бумага тип. Печать офсетная. Тираж 1000 экз. Заказ 1/097.
Отпечатано в ИПК СФУ. 660041 Красноярск, пр. Свободный, 79.
2009 2 (1)
Стр.1
Editorial board for Chemistry:
Nikolai V. Chesnokov
Lubov ’ K. Altunina
Natalia G. Bazarnova
Vasiliy A. Babkin
Vicente Cebolla
Viktor M. Denisov
Zinfer R. Ismagilov
Sergey V. Kachin
Sergey D. Kirik
Wolfgang Klose
Vladimir I. Kovalchuk
Vladimir A. Likholobov
Yuri L. Mikhlin
Gennady L. Pashkov
Anatoly I. Rubailo
Tatyana V. Ryazanova
Vladimir A. Sobyanin
Valeri E. Tarabanko
Tatyana G. Shendrik
Maxim L. Shchipko
Jean V. Weber
Å.À. Вишнякова, Ñ.Â. Ñàéêîâà, Ñ.Ì. Æàðêîâ,
Ì.Í. Ëèõàöêèé, Þ.Ë. Михлин
Определение условий образования наночастиц серебра
при восстановлении глюкозой в водных растворах
– 48 –
Л.Г. Бондарева, Н.В. Помозова
Изучение влияния различных типов тушения на эффективность
измерений трития в объектах окружающей среды
– 56 –
Í.Â. ×àåíêî, Â.Ë. Корниенко, Ã.Â. Корниенко
Редокс-медиаторное окисление алифатических спиртов
до карбоновых кислот на гидрофобизированных оксидноникелевых
и оксидно-кобальтовых электродах
– 64 –
È.Ñ. ßêèìîâ, Ï.Ñ. Äóáèíèí, Î.Å. Пиксина
Регуляризация метода ссылочных интенсивностей для
количественного рентгенофазового анализа поликристаллов
– 71 –
Свидетельство о регистрации СМИ
ПИ № ФС77-28-726 от 29.06.2007 г.
М.А. Шестопалов, Ж.С. Кожомуратова,
А.И. Смоленцев, Ю.В. Миронов, Андрэ Перрин,
Кристин Перрин, В.Е. Федоров
Строение нового октаэдрического кластерного комплекса рения
–
[цис-Ca(OPPh3
)4
(H2
O)2
][{Re6
(μ3
-S)6
– 81 –
(μ3
-Br)2
}Br6
]•2CH3
CN
Стр.2
Journal of Siberian Federal University. Chemistry 1 (2009 2) 3-10
~ ~ ~
УДК 553.93:66.094.7
Study of High Porous Carbons Prepared
by the Alkaline Activation of Anthracites
Nadezhda M. Mikovaa
, Nikolai V. Chesnokova,b
and Boris N. Kuznetsova,b
42 K.Marx st., Krasnoyarsk, 660049 Russia
b
*
a Institute of Chemistry and Chemical Technology SB RAS,
Siberian Federal University,
79 Svobodny, Krasnoyarsk, 660041 Russia 1
Received 02.03.2009, received in revised form 10.03.2009, accepted 25.03.2009
The influence of alkaline activation on the development of anthracite porous structure under the
variation of different factors: anthracite and metal hydroxide origin, their mass ratio in a mixture,
activation temperature and duration has been studied. The highest development of anthracite surface
area was reached with mass ratio of anthracite/alkali 1:5-7 and the final heating temperature of 800 °С.
Under these conditions the maximum value of surface area of carbon material was 2900 m2
КОН activated Siberian anthracite and 2550 m2
/g in case of
/g for NaOH activated Ilovaisky anthracite.
Keywords: porous carbons, preparation, anthracites, alkaline activation, surface area.
Introduction
Chemical activation is now widely used
for preparation of porous carbon materials from
solid fossil fuel [1]. From the point of view of
accessibility and effectivity, the most interesting
and promising are alkaline metal hydroxides
(NaOH, КОН) used as reagents for chemical
activation of carbon raw precursors [2-4]. Treating
fossil coals with different in nature alkaline
reagents, varying their amount, experimental
technique of alkaline hydroxide interaction
with coal and the activation process conditions
it is possible to vary the final properties and
characteristics of the obtained porous carbons.
Chemical activation of natural anthracites which
have a developed system of the germinal micro
* Corresponding author E-mail address: cnv@icct.ru
1
© Siberian Federal University. All rights reserved
– 3 –
pores by means of alkaline metal compounds can
be considered as a promising method, providing
the further development of porous structure
and preparation of carbon materials with a high
surface area [5-8].
In this study the general regularities of
the nanoporous carbon structure formation of
Siberian and Ilovaisky anthracites in presence of
alkaline metal hydroxides have been investigated
at various pyrolysis conditions.
Experimental
The samples of two natural anthracites
of Ilovaisky (Ukraine) and Siberian (Kuzbass)
deposits were selected as the objects for research.
The characteristics of the original coals are
Стр.3