Журнал Сибирского федерального университета
Journal of Siberian Federal University
Химия
Chemistry
Редакционный совет
академик РАН Е.А.Ваганов
академик РАН К.С.Александров
академик РАН И.И.Гительзон
академик РАН В.Ф.Шабанов
чл.-к. РАН, д-р физ.-мат.наук
А.Г.Дегерменджи
чл.-к. РАН, д-р физ.-мат. наук
В.Л.Миронов
чл.-к. РАН, д-р техн. наук
Г.Л.Пашков
чл.-к. РАН, д-р физ.-мат. наук
В.В.Шайдуров
чл.-к. РАО, д-р физ.-мат. наук
В.С. Соколов
Editorial Advisory Board
Chairman:
Eugene A. Vaganov
Members:
Kirill S. Alexandrov
Josef J. Gitelzon
Vasily F. Shabanov
Andrey G. Degermendzhy
Valery L. Mironov
Gennady L. Pashkov
Vladimir V. Shaidurov
Veniamin S. Sokolov
Editorial Board:
Editor-in-Chief:
Mikhail I. Gladyshev
Founding Editor:
Vladimir I. Kolmakov
Managing Editor:
Olga F. Alexandrova
Executive Editor for Chemistry:
Boris N. Kuznetsov
Редактор И.А. Вейсиг Корректор Т.Е. Бастрыгина
Компьютерная верстка И.В. Гревцовой
Подписано в печать 27.08.2008 г. Формат 19х27. Усл. печ. л. 10,6.
Уч.-изд. л. 10,1. Бумага тип. Печать офсетная. Тираж 1000 экз. Заказ 1/063.
Отпечатано в ИПК СФУ. 660041 Красноярск, пр. Свободный, 79.
CONTENTS / СОДЕРЖАНИЕ
Valentina V. Simonova, Tatyana G. Shendrik,
Vladimir A. Kucherenko, Nikolai V. Chesnokov
and Boris N. Kuznetsov
Study of Thermochemical Transformations of Hydrolytic Lignin
and the Properties of the Produced Active Carbons
– 107 –
Valeri E. Tarabanko, Konstantin L. Kaygorodov
and Mikhail Yu. Chernyak
Polyesterification of Alpha-Angelicalactone
– 118 –
Boris N. Kuznetsov, Vladimir I. Kovalchuk,
Nadezhda M. Mikova, Nikolai V. Chesnokov
and Liliya V. Naimushina
Formation of Iron Nanoparticles by Thermal
Transformations of Iron Carbonyls on Silica Surface
– 124 –
Viktoriya V. Sursyakova, Sergey N. Kalyakin,
Galina V. Burmakina and Anatoliy I. Rubaylo
Measurement of Ion Association Constants from Decrease of
Peak Areas by Capillary Electrophoresis Technique with Indirect
Spectrophotometric Detection
– 136 –
Юрий Л. Михлин, Максим Н. Лихацкий,
Ирина А. Ярославцева, Зинаида В. Борисова
hƒ3че…,е ,мм%K,л,ƒ%"=……/. C!%д3*2%" “3ль-,д…%г%
"%““2=…%"ле…, 2е2!=.л%!=3!=2-,%…%"
– 142 –
2008 1 (2)
Стр.1
Editorial board for Chemistry:
Nikolai V. Chesnokov
Lubov ’ K. Altunina
Natalia G. Bazarnova
Vasiliy A. Babkin
Vicente Cebolla
Viktor M. Denisov
Zinfer R. Ismagilov
Sergey V. Kachin
Sergey D. Kirik
Wolfgang Klose
Vladimir I. Kovalchuk
Vladimir A. Likholobov
Yuri L. Mikhlin
Gennady L. Pashkov
Anatoly I. Rubailo
Tatyana V. Ryazanova
Vladimir A. Sobyanin
Valeri E. Tarabanko
Tatyana G. Shendrik
Maxim L. Shchipko
Jean V. Weber
Светлана А. Кузнецова, Наталья Ю. Васильева,
Галина С. Калачева, Надежда М. Титова,
Евгения С. Редькина, Галина П. Скворцова
o%л3че…,е д,=це2=2= Kе23л,…= ,ƒ Kе!е“2/ *%!/ Kе!еƒ/ ,
,ƒ3че…,е ег% =…2,%*“,д=…2…%L =*2,"…%“2,
– 151 –
Максим Л. Щипко, Анна О. Еремина,
Валентина В. Головина
`д“%!Kе…2/ ,ƒ 3гле!%д“%де!›=?ег% “/!ь j!=“…% !“*%г%
*!=
– 166 –
Светлана А. Кузнецова, Владимир Г. Данилов,
Ольга В. Яценкова, Наталья М. Иванченко,
Наталья Б. Александрова
nC2,м,ƒ=ц, C!%це““= дел,г…,-,*=ц,, д!е"е“,…/ %“,…/
3*“3“…%L *,“л%2%L " C!,“32“2",, Cе!%*“,д= "%д%!%д= ,
“е!…%-*,“л%2…%г% *=2=л,ƒ=2%!=
– 181 –
Свидетельство о регистрации СМИ
ПИ № ФС77-28-726 от 29.06.2007 г.
Светлана С. Лалетина, Алексей М. Шор,
Елена А. Шор, Владимир А. Наслузов,
Анатолий И. Рубайло
hƒ3че…,е *%%!д,…=ц,, *=2,%…= д,*=!K%…,л= !%д, (I) …=
це%л,2е ме2%д%м DFT
– 190 –
Тамара И. Когай
q,…2еƒ “л%›…/. .-,!%" Kе23л,…=
– 200 –
Олег В. Белоусов, Роман В. Борисов,
Владимир А. Парфенов, Юрий В. Салтыков
nце…*= 3дель…%L C%"е!.…%“2, C%!%ш*%" C=лл=д, ме2%д%м
ц,*л,че“*%L "%ль2=мCе!%ме2!,,
– 206 –
Стр.2
Valentina V. Simonova, Tatyana G. Shendrik… Study of Thermochemical Transformations of Hydrolytic Lignin…
Journal of Siberian Federal University. Chemistry 2 (2008 1) 107-117
~ ~ ~
УДК 544.478.32
Study of Thermochemical Transformations of Hydrolytic Lignin
and the Properties of the Produced Active Carbons
Valentina V. Simonovaa
Vladimir A. Kucherenkoa
a
, Tatyana G. Shendrika
, Nikolai V. Chesnokovb,c
and Boris N. Kuznetsovb,c
79 Svobodny, Krasnoyarsk, 660041 Russia
c
Institute of Chemistry and Chemical Technology SB RAS,
42 K.Marx st., Krasnoyarsk, 660049 Russia 1
Received 2.06.2008, received in revised form 25.08.2008, accepted 27.08.2008
There has been studied the infl uence of the conditions of heat treatment of hydrolytic lignin and its
mixtures with oil slime on the yield, structure and adsorption properties of active carbons (AC). With
the increase in the temperature of lignin processing from 400 to 900 ˚C, the yield of active carbon
decreases, and its specifi c surface area and sorption activity reach the maximum values at 800 ˚C.
The mutual infl uence of the components of the mixture of hydrolytic lignin and oil slime during the
thermochemical transformations, becomes apparent in the variation of the yield and the porous structure
of AC. As for the oil slime, it acts as a binding and structure forming component.
Keywords: hydrolytic lignin, oil slime, thermal transformations, active carbon, structure, adsorption
properties.
The technical lignin which is formed during
the chemical processing of wood at the paper and
pulp and hydrolytic plants, is the waste which
is the most diffi cult to utilize. The amount of
unutilized lignins in the Ukraine (that is the waste
of the yeast, forage and paper and pulp industries)
makes up, according to different data, from 5 to
15 million tons, whereas in Russia and Belarus
their number is greater [1]. At present there are no
exhaustive technical solutions on utilizing lignins,
although the survey of the scientifi c literature for
* Corresponding author E-mail address: bnk@icct.ru
1
© Siberian Federal University. All rights reserved
# 107 #
the past years is evidence of the great interest that
the researchers show in this raw material.
Lignin is a polymer of aromatic nature.
Its structural unit is presented mainly by
phenylpropane units [2]. The variety of
connections between the latter determines the
irregular molecule lignin structure [3]. Lignin is
a polyfunctional substance, containing phenolic,
alcoholic, carbonyl, acidic and methoxyl groups.
The number of these groups varies greatly
depending on the industrial hydrolysis conditions,
,
*
Institute of Physical and Organic Chemistry and Coal Chemistry, NAS,
Siberian Federal University,
70 R. Luxemburg st., Donetsk, 831114 Ukraine
b
Стр.3