Учредитель – Федеральное государственное бюджетное образовательное учреждение
высшего профессионального образования «Южно-Уральский государственный
университет» (национальный исследовательский университет)
Журнал публикует рецензированные статьи по научным исследованиям, выполненным в различных
отраслях химической науки: неорганическая химия, органическая химия, аналитическая химия, физическая
химия и химия твёрдого тела. <...> В.;
PhD, Full Professor (Spain) Garcia J.R.;
PhD (Spain) Khainakov S.A.
South Ural State University
The journal publishes peer-reviewed papers on scientific research in various branches of chemical science:
inorganic chemistry, organic chemistry, analytical chemistry, physical chemistry and solid-state chemistry. <...> Editorial board
V.V. Sharutin, Doctor of Science (Chemistry), Full Professor, South Ural State University,
Chelyabinsk, Russian Federation
V.V. Avdin, Doctor of Science (Chemistry), Full Professor, South Ural State University,
Chelyabinsk, Russian Federation
T.V. Mosunova, PhD (Chemistry), Associate professor, South Ural State University, Chelyabinsk,
Russian Federation
D.G. Kim, Doctor of Science (Chemistry), Full Professor, South Ural State University, Chelyabinsk,
Russian Federation
V.G. Bamburov, Doctor of Science (Chemistry), Full Professor, corresponding member of the
Russian Academy of Sciences, The Institute of Solid State Chemistry, Ekaterinburg, Russian
Federation
V.L. Rusinov, Doctor of Science (Chemistry), Full Professor, corresponding member of the Russian
Academy of Sciences, The Institute of Organic Synthesis, Ekaterinburg, Russian Federation
O.K. Sharutina, Doctor of Science (Chemistry), Full Professor, South Ural State University,
Chelyabinsk, Russian Federation
Е. <...> Molecular Structures
of Bis[µ2-oxotri(o-tolyl)antimony] and µ2 oxo-bis[(tert-butylperoxy)tri(o-tolyl)antimony] .............. 23
ARTEMOV A.N., SAZONOVA E.V., ZAROVKINA N.YU., FAERMAN V.I. Chemistry
of unsaturated arenetricarbonylchromium compounds. <...> Synthesis, characteristics
and spectroscopic research of η6-(arene)tricarbonylchromium derivatives of isoxazolidines ............ 30
SHARUTIN V.V., SHARUTINA O.K., SENCHURIN V.S., KHISAMOV R.M., MOSUNOVA T.V.
Synthesis and structure of bismuth complexes [p-Tol4E]+3[Bi3I12]3–HOCH2CH2OC2H5 E=P, Sb ..... 44
KAZANTSEV O.A., RUMYANTSEV M.S., SAVINOVA M.V., KHOKHLOVA <...>
Вестник_Южно-Уральского_государственного_университета._Серия_Химия_№4_2015.pdf
Учредитель – Федеральное государственное бюджетное образовательное учреждение
высшего профессионального образования «Южно-Уральский государственный
университет» (национальный исследовательский университет)
Журнал публикует рецензированные статьи по научным исследованиям, выполненным в различных
отраслях химической науки: неорганическая химия, органическая химия, аналитическая химия, физическая
химия и химия твёрдого тела. Приветствуется публикация статей по смежным отраслям. Редакционная
коллегия поддерживает высокий уровень публикаций, строго придерживаясь политики независимой
сторонней экспертизы, выполненной специалистами в соответствующей области, квалификация которых
подтверждена общепризнанными наукометрическими показателями.
Основной целью журнала является пропаганда актуальных научных исследований и содействие
формированию наиболее перспективных направлений.
Редакционная коллегия
д.х.н., проф. Шарутин В.В.
(отв. редактор);
д.х.н., проф. Авдин В.В.
(зам. отв. редактора);
к.х.н., доцент Мосунова Т.В.
(отв. секретарь);
д.х.н., проф. Ким Д.Г.
д.х.н., проф., чл.-корр. РАН Бамбуров В.Г.;
д.х.н., проф., чл.-корр. РАН Русинов В.Л.;
д.х.н., проф. Шарутина О.К.;
д.х.н., проф. Климов Е.С.;
д.х.н., проф. Гущин А.В.;
PhD, Full Professor (Spain) Garcia J.R.;
PhD (Spain) Khainakov S.A.
Стр.1
South Ural State University
The journal publishes peer-reviewed papers on scientific research in various branches of chemical science:
inorganic chemistry, organic chemistry, analytical chemistry, physical chemistry and solid-state chemistry. The
papers in related branches are welcome. The editorial board keeps the high quality of publications, strictly adhering
to the policy of independent third-party expert opinion, expressed by specialists in the corresponding branches,
whose qualification is confirmed by generally recognized scientometrical indicators.
The main aim of the journal is the promotion of actual scientific research and assistance in formation of the
most advanced directions.
Editorial board
V.V. Sharutin, Doctor of Science (Chemistry), Full Professor, South Ural State University,
Chelyabinsk, Russian Federation
V.V. Avdin, Doctor of Science (Chemistry), Full Professor, South Ural State University,
Chelyabinsk, Russian Federation
T.V. Mosunova, PhD (Chemistry), Associate professor, South Ural State University, Chelyabinsk,
Russian Federation
D.G. Kim, Doctor of Science (Chemistry), Full Professor, South Ural State University, Chelyabinsk,
Russian Federation
V.G. Bamburov, Doctor of Science (Chemistry), Full Professor, corresponding member of the
Russian Academy of Sciences, The Institute of Solid State Chemistry, Ekaterinburg, Russian
Federation
V.L. Rusinov, Doctor of Science (Chemistry), Full Professor, corresponding member of the Russian
Academy of Sciences, The Institute of Organic Synthesis, Ekaterinburg, Russian Federation
O.K. Sharutina, Doctor of Science (Chemistry), Full Professor, South Ural State University,
Chelyabinsk, Russian Federation
Е.S. Klimov, Doctor of Science (Chemistry), Full Professor, Ulyanovsk State Technical University,
Ulyanovsk, Russian Federation
A.V. Gushchin, Doctor of Science (Chemistry), Full Professor, Lobachevsky State University of
Nizhny Novgorod, Nizhny Novgorod, Russian Federation
J.R. García, PhD, Full Professor, University of Oviedo, Oviedo, Spain
S.A. Khainakov, PhD, Researcher, University of Oviedo, Mieres, Spain
Стр.2
CONTENTS
Organometallic Chemistry
Grigory Alekseyevich Razuvaev ........................................................................................................ 4
GUSHCHIN A.V. Keeping Razuvaev's Traditions Alive .................................................................. 5
RAZUVAEV G.A., SHARUTIN V.V. Some reactions of bis(cyclopentadienyl)diferrocenyltitan ... 9
SHARUTIN V.V., SHARUTINA O.K., SENCHURIN V.S. Synthesis and Structure of Osmium
Complex [Ph4P]2[OsBr6]. .................................................................................................................... 13
SHARUTIN V.V., SHARUTINA O.K., GUBANOVA Yu.O. Interaction of Pentaphenylantimony
with Acetylenedicarboxylic Acid. Molecular Structure of Bis(tetraphenylantimony)
Acetylenedicarboxilate ....................................................................................................................... 17
SHARUTIN V.V., SHARUTINA O.K., ARTEM'EVA E.V., MAKEROVA M.S.
Oxidation of Tri(o-tolyl)antimony by Tert Butyl Hydroperoxide. Molecular Structures
of Bis[µ2-oxotri(o-tolyl)antimony] and µ2 oxo-bis[(tert-butylperoxy)tri(o-tolyl)antimony] .............. 23
ARTEMOV A.N., SAZONOVA E.V., ZAROVKINA N.YU., FAERMAN V.I. Chemistry
of unsaturated arenetricarbonylchromium compounds. Part 3. Synthesis, characteristics
and spectroscopic research of η6-(arene)tricarbonylchromium derivatives of isoxazolidines ............ 30
SHARUTIN V.V., SHARUTINA O.K., SENCHURIN V.S., KHISAMOV R.M., MOSUNOVA T.V.
Synthesis and structure of bismuth complexes [p-Tol4E]+
3[Bi3I12]3–HOCH2CH2OC2H5 E=P, Sb ..... 44
KAZANTSEV O.A., RUMYANTSEV M.S., SAVINOVA M.V., KHOKHLOVA T.A.,
DANOV S.M., SADIKOV A.Yu. Synthesis of polyacryl thickeners by radical precipitation
polymerization ..........................................................................................................................................
52
SEMENYCHEVA L.L., KUZNETSOVA YU.L., GERASKINA E.V., MATKIVSKAYA Yu.O.,
MOIKIN A.A. Influence of synthesis conditions on composition of alkyl (meth)acrylate–vinyl
alkyl ether copolimers ...............................................................................................................................
SEMENOV V.V. Reaction of 3-aminopropyltriethoxysilane with triphenylphosphate ..........................
59
66
SHARUTIN V.V. SHARUTINA O.K., SENCHURIN V.S. Synthesis and structure of iridium
complex [Ph4Sb(DMSO)]+[IrCl4(DMSO)2]– .............................................................................................
80
SHARUTIN V.V. SHARUTINA O.K., SENCHURIN V.S. Synthesis and structure of tri- and
tetraphenylantimony aroxides: Ph3Sb[OC6H3(Br2-2,6)(Me-4)]2 and Ph4SbOC6H3Br2-2,6, Me-4 ............
86
SHARUTIN V.V. SHARUTINA O.K., SENCHURIN V.S. Synthesis and structure of tri(metatolyl)antimony
bis(benzenesulfonate) .......................................................................................................
93
SHARUTIN V.V. SHARUTINA O.K., SENCHURIN V.S. Synthesis and structure of gold
complexes [p-Tol4Sb][p-TolAuCl3] and [p-Tol4Sb][AuCl4] ................................................................ 98
© Издательский центр ЮУрГУ, 2015
Стр.3
Organometallic Chemistry
The issue is composed of papers
dedicated to the memory of
the outstanding chemist
academician G.A. Razuvaev
in relation to 120th anniversary
of his birthday
Grigory Alekseyevich Razuvaev
(18951989)
On August 23, 2015, is the 120th anniversary from the
birthday of academician Grigory Alekseyevich Razuvaev, who
was an outstanding scientist, one of the founders of the modern
organometallic chemistry.
Grigory Alekseyevich Razuvaev was born on August 23,
1895, in Moscow. He graduated from Leningrad University
(1925). From 1927 he worked in the laboratory of research in
high pressures (State Institute of High Pressures from 1929) and
Leningrad Technological Institute.
Since 1946 he was a professor of Gorky State University
and simultaneously the director of Scientific Research Institute
of the university in 1956–1962. In 1963 he was made the head
of the laboratory of polymer stabilization of the USSR Academy
of Sciences. In 1969–1988 he was the director of Chemistry Institute
of the USSR Academy of Sciences in Gorky. Since 1988
he was the honorary director of
Institute of Organometallic
Chemistry of the USSR Academy of Sciences.
His fundamental research was in chemistry of organometallic
compounds, organic peroxides and in the study of free radicals in solutions. He determined the relative
rate of their formation during thermal decomposition of organomercury compounds and compiled
the activity series for radicals. Together with M.M. Koton he discovered the method of generation of
free aliphatic radicals (1931–1935). He established the mechanism (1940s) of free radical formation in
photolysis reactions of organometallic compounds in liquid medium, as well as the character of their
interaction with each other and the solvents. He developed a new accessible synthesis method of mercury
organic compounds (1954) by the action of free radicals formed from peroxides upon mercury
salts. He discovered fundamentally new ways of transfromations in the series of arsenic organic derivatives.
He suggested synthesis methods (1963–1969) of organometallic compounds with a chain containing
from two to four heteroatoms of the R3SiHgGeR3 type. Together with his collaborators (1963–1970)
he originated various ways to obtain filamentary single crystals and layered films of germanium and
other metals for semiconductor technology and electronics. He obtained organometallic compounds,
used as polymerization initiators and catalysts and as monomer stabilizers. In 1967–1974 he developed
synthesis methods of cenyl aryl compounds of tetravalent titanium, zirconium, vanadium and trivalent
titanium.
G.A. Razuvaev was awarded the title of Hero of Socialist Labour (1969), Lenin Prize (1958), State
Prizes of the USSR (1971, 1985).
4
Bulletin of the South Ural State University. Ser. Chemistry.
2015, vol. 7, no. 4, p. 4
Стр.4