Журнал Сибирского федерального университета
Journal of Siberian Federal University
Химия
Chemistry
Редакционный совет
академик РАН Е.А.Ваганов
академик РАН К.С.Александров
академик РАН И.И.Гительзон
академик РАН В.Ф.Шабанов
чл.-к. РАН, д-р физ.-мат.наук
А.Г.Дегерменджи
чл.-к. РАН, д-р физ.-мат. наук
В.Л.Миронов
чл.-к. РАН, д-р техн. наук
Г.Л.Пашков
чл.-к. РАН, д-р физ.-мат. наук
В.В.Шайдуров
чл.-к. РАО, д-р физ.-мат. наук
В.С. Соколов
член-корр. РАН, д-р физ.-мат. наук
В.В. Зуев
Editorial Advisory Board
Chairman:
Eugene A. Vaganov
Members:
Kirill S. Alexandrov
Josef J. Gitelzon
Vasily F. Shabanov
Andrey G. Degermendzhy
Valery L. Mironov
Gennady L. Pashkov
Vladimir V. Shaidurov
Veniamin S. Sokolov
Editorial Board:
Editor-in-Chief:
Mikhail I. Gladyshev
Founding Editor:
Vladimir I. Kolmakov
Managing Editor:
Olga F. Alexandrova
Executive Editor for Chemistry:
Boris N. Kuznetsov
CONTENTS / СОДЕРЖАНИЕ
Alexandra R. Akhmedova, Olga V. Serebrennikova
and Olga V. Shiganova
Composition of Mono-, Bi- and Tricyclic Aromatic Hydrocarbons
in Oils from the Middle part of the East Siberia
– 329 –
Â.Â. Ñèìîíîâà, Ò.Ã. Øåíäðèê, Á.Í. Кузнецов
lе2%д/ 32,л,ƒ=ц,, 2е.…,че“*,. л,г…,…%"
– 340 –
Â.Í. Ëîñåâ, Î.Â. Áóéêî, Á.À. Величко
q%!Kц,%……%е *%…це…2!,!%"=…,е , “%!Kц,%……%-=2%м…%.м,““,%……%е
%C!еделе…,е ƒ%л%2= , C=лл=д, “ ,“C%льƒ%"=…,ем
-,2%“%!Kе…2=
– 355 –
И.В. Петерсон, В.А. Соколенко,
Н.М. Свирская, А.И. Рубайло
q,…2еƒ =д=м=…2,ль…/. C!%,ƒ"%д…/. 1,6- , 1,7д,г,д!%*“,…=-2=л,…%"
–
362 –
В.П. Твердохлебов, С.А. Храменко,
Ô.À. Áóðþêèí, È.Â. Ïàâëîâ, Ñ.Å. Прошкин
mе-2 …%L *%*“ дл
Šе.…%л%г, , “"%L“2"=
– 369 –
Е.С. Роговенко, Н.В. Блинникова,
À.À. Øóáèí, Ë.Ã. Бондарева
}*%л%г,че“*,q *%…2!%ль =…2!%C%ге……%г% ƒ=г! ƒ…е…, “…ег%"%г%
C%*!%"= %д…%г% ,ƒ C!%м/шле……/. !=L%…%" г. j!=“…% !“*=
– 387 –
Редактор И.А. Вейсиг Корректор Т.Е. Бастрыгина
Компьютерная верстка Е.В. Гревцовой
Подписано в печать 17.12.2010 г. Формат 84х108/16. Усл. печ. л. 8,45.
Уч.-изд. л. 7,9. Бумага тип. Печать офсетная. Тираж 1000 экз. Заказ 3742.
Отпечатано в ПЦ БИК СФУ. 660041 Красноярск, пр. Свободный, 82a.
=люм,…,е"%L C!%м/шле……%“2,.
2010 3 (4)
Стр.1
Editorial board for Chemistry:
Nikolai V. Chesnokov
Lubov ’ K. Altunina
Natalia G. Bazarnova
Vasiliy A. Babkin
Vicente Cebolla
Viktor M. Denisov
Zinfer R. Ismagilov
Sergey V. Kachin
Sergey D. Kirik
Wolfgang Klose
Vladimir I. Kovalchuk
Vladimir A. Likholobov
Yuri L. Mikhlin
Gennady L. Pashkov
Anatoly I. Rubailo
Tatyana V. Ryazanova
Vladimir A. Sobyanin
Valeri E. Tarabanko
Tatyana G. Shendrik
Maxim L. Shchipko
Jean V. Weber
Ã.Å. Ñåëþòèí, Þ.Þ. Ãàâðèëîâ,
О.Е. Попова, Е.Н. Воскресенская
p=ƒ!=K%2*= !еƒ,…%C%л,ме!…/. =!м,!%"=……/. м=2е!,=л%" дл
!=K%2/ " 3“л%", . "/“%*,. д="ле…,L
– 396 –
Å.È. Ëåñèê, Å.Ñ. Семиченко,
А.В. Лесничев, В.Д. Ворончихин
`…2,%*“,д=…2…= =*2,"…%“2ь C!%“2!=…“2"е……%-ƒ=2!3д…ё……/.
=…,л,…%"
– 403 –
Ë.Ñ. Ñîêîëîâà, Å.Ã. Ñòðóêîâà, Î.À. Дукова
u!%м=2%-м=““-“Cе*2!%ме2!,че“*%е %C!еделе…,е …е*%2%!/.
›е…“*,. C%л%"/. г%!м%…%" “2е!%,д…%г% “2!%е…, , ,.
“,…2е2,че“*,. =…=л%г%"
– 408 –
Ë.Ã. Áàáåøèíà, ß.Â. Ãîðèíà,
À.Ï. Колоколова, Å.À. Êðàñíîâ, Ì.Ð. Карпова
h““лед%"=…,е C%л,“=.=!,д%" …е*%2%!/. ",д%" !%д=
Sphagnum L.
– 413 –
Свидетельство о регистрации СМИ
ПИ № ФС77-28-726 от 29.06.2007 г.
Серия включена в «Перечень ведущих
рецензируемых научных журналов
и изданий, в которых должны
быть опубликованы основные научные
результаты диссертации на
соискание ученой степени доктора и
кандидата наук» (редакция 2010 г.)
Â.À. Ôåäîðîâ,
Н.В. Вологдин, П.В. Фабинский
hƒ3че…,е
C%л,2е!м,че“*%L !=“2"%!,м%“2,
– 423 –
2!,“=це2,л=це2%…=2%"
.!%м= (III) , *%K=ль2= (III) " "%д…%ме2=…%ль…/.
!=“2"%!,2ел .
Стр.2
Journal of Siberian Federal University. Chemistry 4 (2010 3) 329-339
~ ~ ~
УДК 665.61.550.43
Composition of Mono-, Biand
Tricyclic Aromatic Hydrocarbons
in Oils from the Middle part of the East Siberia
Olga V. Serebrennikovab
a
b
Alexandra R. Akhmedovaa
and Olga V. Shiganovaa
*,
Siberian Research Institute of Geology, Geophysics
and Mineral Resources (SRIGGAMR),
67 Krasny prospect, Novosibirsk, 630091 Rassia
Institute of Petroleum Chemistry, Russian Academy
of Science, Siberian Branch,
4 Akademichesky, Tomsk, 634021 Rassia 1
Received 3.12.2010, received in revised form 10.12.2010, accepted 17.12.2010
Aromatic hydrocarbons composition of oils was determined by the GC-MS method. Analysis of the
results showed that there is a wide variety of alkyl-substituted benzenes, naphthalenes, fl uorenes
and phenanthrenes. Relative concentrations of special types of arenes varies in different oils; but in
the most part of oils alkylbenzenes are the most representative type of arenes.
Keywords: areny, biomarker, East Siberia, oil, aromatic hydrocarbons.
Introduction
As usual aromatic hydrocarbons (HC) are
the part of all crude oils; they present in oil in
some defi nite concentrations. The properties of
oil and the ways of oil refi ning depend on the
quantity of aromatic HC in crude oil. Oil arenes
are investigated in details; the results are reported
in numerous papers but as usual all articles are
concerned with the western parts of Russia
including the territory of the West Siberia. In
spite of the East Siberia has a sizeable discovered
recoverable reserve of HC and famous oil pipeline
“East Siberia – Pacifi c Ocean” is constructed in
this area, the data of arenes concentrations in the
East Siberia oils are quiet limited.
© Siberian Federal University. All rights reserved
The information of linear alkylbenzenes
C17-C23 in three types of crude oil of NepaBotuobinskaya
oil-and-gas bearing region
(OGBR) is presented in [1]. These oils mostly
contain linear alkylbenzenes with an odd number
of C atoms [1]. In papers [2, 3] the data of arenes
content in oil and natural bitumens of Devonian
deposits in Khakassia are presented. It is shown
that
3-methylalkylbenzenes
with
isoprene
chain C4-C13 are prevalent in oil arenes and
polyphenyles (polycyclic aromatic HC with 3-4
phenyl radicals) are found in bitumens [2, 3].
Paper [4] applies to the detailed investigation
of aromatic HC in the Jurassic and the Paleozoic
oils of
the West-Siberian oil-and-gas province
* Corresponding author E-mail address: Ahmedova-sniiggims@yandex.ru
1
# 329 #
Стр.3