Известия высших учебных заведений. Серия "Химия и химическая технология" №8 2015 (190,00 руб.)

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 58 (8)   2015  547.1, 547.8 . , . , . , .   .  ) e-mail: reaktiv2003@mail.ru      . ,  40 , , . .   1,3-,   ,   ,   .  .  . : , , , , , , , ,           (,  , , , .)  –  ( 1993 .   – ),   60- . . .     [1-18]. 1.   1,3-           (,   .)   (). .      . . .        4--1,3- [19-34]. C=C  H+ + CH2O + CH2OH C C CH2OH CH2O CH2OH + C C CH2OH C C CH2OH O CH2 - H O O +   -   . ,   .         .  (),     [33, 34]. .           [1-3, 5, 9, 12, 14-16]. C (C)n C OH n = 0,1,2  ,     ,        – 1,3- [3, 17]. R1 R O + R1CH NR2 O NR R  1,3- -2   . .  [35-43].  2015  58 . 8 3 + CO OH H+ - H2O O ( )n O

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R2 R R'  OH ( )n R3 C OH n = 0, 1 R7 R2 R4 R5 R' + R6R7SiCl2 2HCl R O ( )n Si R3 O R6       ( )  . ,  72-81% [38, 39]. R1 R2 R5 O O R6 R3 R4 + MeSi(OR7)3 H+ R1 O Me OR7 Si      - -  [3, 17, 18]. 2.       , , , ,   , , , -, -,   .       -   ,      ,  1,3-.  [1, 12, 17, 18, 44-72]        , . O O ( )n R    .     .        ,        : [ (CH3)3CO ]2 (CH3)3CO + k1 O O R O O R . 4 2(CH3)3CO (CH3)3COH + O O R . k2 R COOCH2CH2CH2 . (0) (1)  R C O O CH2 (CH2)n CH3 R2 O R3 R4 + R5R6C(OR7)2 R4 R5 RCOOCH2CH2CH2 + . 2RCOOCH2CH2CH2 O . O R . k3 RCOOC3H7 + O O R k4 RCOO(CH2)6OCOR (3) (4)      .  k3/k4,  k3 k4 –      ,  ,  ,        .  -   1,3-     H3C O O O O H3C CH3 H3C (CH3COOCH2)2C(CH3)2 O O O O C3H7OCO O O C3H7OCOCOOC3H7    – 2,4- 1,3-      , . O O ( )n R1 n = 0, 1, 2   – 2-   :  O OR + RH O O               .  1,3-         : (2) O X (CH2)n R R-C-X-CH2-(CH2)n-CH3 O X=NR; S; n=0,1,2  2015  58 . 8 C2H5OC O R R2 R1COOCH2(CH2)nCH2R2 R1COOCH(R2)(CH2)nCH3 O O O O CH3 CH2OCOCH3 CH2OCOCH3 CH3

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      .  [1, 73-79]  –             (- , N- .)          –     .    . , .   ,    . D. + HCl3 D. E + DH. E. E + CHCl2 . D = CHCl2 + DH . +HCl3 . O O R H DH - H.  E. D. + EH . ECl + CHCl2 CHCl2CHCl2 ECHCl2 . E = RCOOCH2CH2  : + CBrCl3 O O R  -CHCl3 RCOOCH2CH2CH2Br D. CHCl2 + [DCl] . ECl O O ( )n H3C H n = 0, 1 + C4H9OCH2CH CH2 O O ( )n H3C CH3 C CH2CH2CH2OC4H9 O OCH2(CH2)nCH2CH22CH2OC4H9  .        2- – 1,3-: O O ( )n R O O O O n = 0, 1 R R O O ( )n R CH O CH2 O OR   .       .-.   .  . .           . O O R + n CH2=CH2  O O R RCOO(CH2CH2) H H2 CH2) H n n+1  N-,           ).    1,3- [80-133]         , . O O H3C O O CH3 + CH2 = CHCH2Cl CH3 C O O (CH2)4 CH2Cl CH2CH2CH2Cl ,       n= 2-15.       1,5-  1,6-    .   2-1,3-  n=4-6  n=8-10     -  .          .       . O O CH3 H CH2=CH Si(CH3)3 O O CH3 + O O H3C CH2CHCH2CH2Si(CH3)3 Si(CH3)3   2--1,3 , ,  2015  58 . 8 5 O O H3C CH2CH2Si(CH3)3 OR

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