Журнал Сибирского федерального университета
Journal of Siberian Federal University
Химия
Chemistry
Редакционный совет
академик РАН Е.А.Ваганов
академик РАН И.И.Гительзон
академик РАН А.Г.Дегерменджи
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чл.-к. РАН, д-р физ.-мат. наук
В.Л.Миронов
чл.-к. РАН, д-р техн. наук
Г.Л.Пашков
чл.-к. РАН, д-р физ.-мат. наук
В.В.Шайдуров
чл.-к. РАН, д-р физ.-мат. наук
В.В. Зуев
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Vladimir V. Zuev
Editorial Board:
Editor-in-Chief:
Mikhail I. Gladyshev
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CONTENTS / СОДЕРЖАНИЕ
Vladimir I. Kovalchuk,
William D. Rhodes and Mark A. McDonald
Dechlorinative Oligomerization of Multiply Chlorinated Methanes
Catalyzed by Activated Carbon Supported Pt-Co
– 3 –
Viktor Ì. Denisov, Oksana V. Kuchumova,
Liubov Ò. Denisova, Natalia V. Belousova,
Liubov G. Chumilina and Sergey A. Istomin
Interaction of Leade Oxide $ Germanium Oxide Melts with
Platinum and Palladium
– 18 –
Yuliya V. Tamarkina, Tatyana G. Shendrik,
Vladimir A. Kucherenko and Tatyana V. Khabarova
Conversion of Alexandriya Brown Coal Into Microporous
Carbons Under Alkali Activation
– 24 –
Liliya À. Irtyugo,
Liubov Ò. Denisova, Victor Ì. Denisov,
Natalia V. Belousova and Àlexander S. Samoilo
Thermal Expansion of Lead Germanate Glass
– 37 –
Yury V. Savinykh, Vu Van Hai,
Olga V. Serebrennikova and Larisa D. Stakhina
Compositional Features of Hydrocarbons in Crude Oils from
South Vietnam and West Siberia
– 41 –
2012 5 (1)
Стр.1
Editorial board for Chemistry:
Nikolai V. Chesnokov
Lubov ’ K. Altunina
Natalia G. Bazarnova
Vasiliy A. Babkin
Vicente Cebolla
Viktor M. Denisov
Zinfer R. Ismagilov
Sergey V. Kachin
Sergey D. Kirik
Wolfgang Klose
Vladimir I. Kovalchuk
Vladimir A. Likholobov
Yuri L. Mikhlin
Gennady L. Pashkov
Anatoly I. Rubailo
Tatyana V. Ryazanova
Vladimir A. Sobyanin
Valeri E. Tarabanko
Tatyana G. Shendrik
Jean V. Weber
Т.П. Шахтшнейдер, С.А. Кузнецова,
Ì.À. Михайленко, Þ.Í. Ìàëÿð,
Г.П. Скворцова, В.В. Болдырев
o%л3че…,е
…е2%*“,ч…/. *%мC%ƒ,2%" Kе23л,…= “
C%л,",…,лC,!!%л,д%…%м , C%л,.2,ле…гл,*%лем
– 52 –
Ñ.Â. Ñàéêîâà, Ñ.À. Âîðîáüåâ, Þ.Ë. Михлин
bл, …,е !е=*ц,%……/. 3“л%",L …= C!%це““ %K!=ƒ%"=…,
…=…%ч=“2,ц мед, C!, "%““2=…%"ле…,, ,%…%" Cu2+
!=“2"%!=м, K%!г,д!,д= …=2!,
– 61 –
Í.È. Ãóìåðîâà, Ê.À. Ñåìåíîâà,
Ã.Ì. Ðîçàíöåâ, Ñ.Â. Радио
nK!=ƒ%"=…,е C%л,%*“%ме2=лл=2-=…,%…%" " C%д*,“ле……/.
"%д…/. !=“2"%!=. "%ль-!=м=2= …=2!, " C!,“32“2",, ,%…%"
Co(II) , Ni(II)
– 73 –
Свидетельство о регистрации СМИ
ПИ № ФС77-28-726 от 29.06.2007 г.
Серия включена в «Перечень ведущих
рецензируемых научных журналов
и изданий, в которых должны
быть опубликованы основные научные
результаты диссертации на
соискание ученой степени доктора и
кандидата наук» (редакция 2010 г.)
Í.Í. Ãîëîâíåâ, À.À. Áàõòèíà, Í.Ì. Коротченко,
Ñ.Ä. Êèðèê, È.È. Головнева, Ë.À. Иртюго
q,…2еƒ , “"%L“2"= “%ед,…е…,L “C=!-л%*“=ц,…=
– 86 –
Î.Â. Òèíüêîâ, Ï.Ã. Ïîëèùóê,
А.Г.Артеменко, В.Е. Кузьмин
h““лед%"=…,е %“2!%L 2%*“,ч…%“2, , -,ƒ,*%-.,м,че“*,.
“"%L“2" %!г=…,че“*,. “%ед,…е…,L
– 95 –
Í.Â. ×àåíêî, Ã.Â. Корниенко,
Н.И. Павленко, В.Л. Корниенко
pед%*“-мед,=2%!…%е %*,“ле…,е глю*%ƒ/ д% глю*%…%"%L
*,“л%2/ …= =…%д=. “ …=…е“е……/м, "/“ш,м, %*“,д=м, …,*ел
" ?ел%ч…%L “!еде
– 105 –
В.В. Симонова, Ю.В. Тамаркина,
В.А. Кучеренко, Т.Г. Шендрик
`д“%!Kц, ,%…%" “",…ц= …=…%C%!,“2/м, м=2е!,=л=м,,
C%л3че……/м, ?ел%ч…%L =*2,"=ц,еL K3!%г% 3гл
– 113 –
"%д…/м,
Стр.2
Journal of Siberian Federal University. Chemistry 1 (2012 5) 3-17
~ ~ ~
УДК 546
Dechlorinative Oligomerization of Multiply Chlorinated
Methanes Catalyzed by Activated Carbon Supported Pt-Co
Vladimir I. Kovalchuka
William D. Rhodesa
,*
and Mark A. McDonaldb
a Department of Chemical and Petroleum Engineering,
University of Pittsburgh, Pittsburgh, PA 15261, United States
b
National Energy Technology Laboratory (NETL),
United States Department of Energy,
Pittsburgh, PA 15236, United States 1
Received 2.03.2012, received in revised form 9.03.2012, accepted 16.03.2012
The hydrodechlorination of dichloromethane, trichloromethane, and their mixtures catalyzed by a PtCo/C
catalyst has been investigated in an effort to elucidate the chemistry associated with the generation
of hydrocarbon oligomerization products.
In the reaction of dichloromethane with hydrogen, the
catalyst did not exhibit deactivation and maintained the steady-state activity within 18 h on stream at
523 K; whereas, when trichloromethane was added or converted in the absence of dichloromethane,
signifi cant deactivation occurred within the fi rst 5 h on stream. Hydrocarbon oligomerization products
were observed with all three reaction mixtures; the selectivity followed the order dichloromethane +
dihydrogen < trichloromethane + dihydrogen < dichloromethane + trichloromethane + dihydrogen.
The generation of ethane and propane was virtually independent of the reaction mixture composition.
However, selectivity toward ethylene and propylene was signifi cantly greater with the trichloromethane
+ dihydrogen and dichloromethane + trichloromethane + dihydrogen mixtures compared to the
dichloromethane + dihydrogen feed. It was concluded that the saturated hydrocarbon products
are formed by means of the alkyl mechanism of hydrocarbon chain growth; whereas, the alkenyl
mechanism is responsible for the formation of the unsaturated hydrocarbons.
Keywords: hydrodechlorination, chloromethanes, dehalogenative oligomerization, Fischer-Tropsch
synthesis, reaction mechanism, platinum, cobalt.
Introduction
The interest in halocarbon chemistry is motivated by the fact that the halogenated molecules remain
important intermediates and products of the chemical process industries [1] and they have detrimental
* Corresponding author E-mail address: vkovalch@gmail.com
1
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