Журнал Сибирского федерального университета
Journal of Siberian Federal University
Химия
Chemistry
Редакционный совет
академик РАН Е.А.Ваганов
академик РАН К.С.Александров
академик РАН И.И.Гительзон
академик РАН В.Ф.Шабанов
чл.-к. РАН, д-р физ.-мат.наук
А.Г.Дегерменджи
чл.-к. РАН, д-р физ.-мат. наук
В.Л.Миронов
чл.-к. РАН, д-р техн. наук
Г.Л.Пашков
чл.-к. РАН, д-р физ.-мат. наук
В.В.Шайдуров
чл.-к. РАО, д-р физ.-мат. наук
В.С. Соколов
Editorial Advisory Board
Chairman:
Eugene A. Vaganov
Members:
Kirill S. Alexandrov
Josef J. Gitelzon
Vasily F. Shabanov
Andrey G. Degermendzhy
Valery L. Mironov
Gennady L. Pashkov
Vladimir V. Shaidurov
Veniamin S. Sokolov
Editorial Board:
Editor-in-Chief:
Mikhail I. Gladyshev
Founding Editor:
Vladimir I. Kolmakov
Managing Editor:
Olga F. Alexandrova
Executive Editor for Chemistry:
Boris N. Kuznetsov
CONTENTS / СОДЕРЖАНИЕ
Olga N. Kononova, Nataliya V. Fyodorova,
Sergey V. Kachin and Alexander G. Kholmogorov
Sorption of Copper (II) from Aqueous Solutions on Complexing
Ion Exchangers and Determination of Copper by Diffuse
Reflectance Spectroscopy
– 195 –
Boris N. Kuznetsov and Maxim L. Shchipko
Wood Waste Steam Gasification to Methane-Enriched Fuel
Gas
– 210 –
Nikolay V. Tarabanko and Valeri E. Tarabanko
A New Vanadium Catalyst for Chlorine Production by Hydrogen
Chloride Oxidation
– 219 –
Â.À. Кучеренко, Ò.Ã. Øåíäðèê, Ò.Â. Õàáàðîâà,
Ю.В. Тамаркина
bл, …,е 2емCе!=23!/ .,м,че“*%L =*2,"=ц,, …= -%!м,!%"=…,е
C%!,“2%L “2!3*23!/ =д“%!Kе…2%" ,ƒ K3!%г% 3гл
– 223 –
Г.Л.Пашков, Н.А.Григорьева, И.Ю.Флейтлих,
Н.И. Павленко, Л.К.Никифорова
}*“2!=*ц, …,*ел , *%K=ль2= , ц,…*= ,ƒ “е!…%*,“л/. !=“2"%!%"
K,“(2,4,4-2!,ме2,лCе…2,л)д,2,%-%“-,…%"%L *,“л%2%L
– 232 –
Ä.Â. Êóçüìèí, Â.È. Êóçüìèí, Ã.Ë. Пашков
h““лед%"=…,е
– 241 –
Редактор И.А. Вейсиг Корректор Т.Е. Бастрыгина
Компьютерная верстка И.В. Гревцовой
Подписано в печать 14.09.2009 г. Формат 84х108/16. Усл. печ. л. 7,2.
Уч.-изд. л. 7,0. Бумага тип. Печать офсетная. Тираж 1000 экз. Заказ 1400.
Отпечатано в ИПК СФУ. 660041 Красноярск, пр. Свободный, 79.
%*,“л,2ель…%-"%““2=…%",2ель…/. “"%L“2"
“,“2ем/ &"%д…/L !=“2"%!-2!,K32,л-%“-=2-.л%!…%"=2,“2=
*,“л%2=[
2009 2 (3)
Стр.1
Editorial board for Chemistry:
Nikolai V. Chesnokov
Lubov ’ K. Altunina
Natalia G. Bazarnova
Vasiliy A. Babkin
Vicente Cebolla
Viktor M. Denisov
Zinfer R. Ismagilov
Sergey V. Kachin
Sergey D. Kirik
Wolfgang Klose
Vladimir I. Kovalchuk
Vladimir A. Likholobov
Yuri L. Mikhlin
Gennady L. Pashkov
Anatoly I. Rubailo
Tatyana V. Ryazanova
Vladimir A. Sobyanin
Valeri E. Tarabanko
Tatyana G. Shendrik
Maxim L. Shchipko
Jean V. Weber
Â.Í. Ëîñåâ, Ñ.È. Метелица
q%!Kц,%……%-люм,…е“це…2…%е %C!еделе…,е =люм,…, “ ,“C%льƒ%"=…,ем
*!ем…еƒем=, м%д,-,ц,!%"=……%г% C%л,ге*“=ме2,ле…г3=…,д,…%м
, 8-%*“,.,…%л,…-5-“3ль-%*,“л%2%L
– 246 –
Н.В. Белоусова, Е.О. Архипова
p=“че2 2е!м%д,…=м,че“*,. “"%L“2" ",“м32=2%" “",…ц=
– 254 –
Ì.Â. Сержантова, À.À. Êóçóáîâ, Ï.Â. Àâðàìîâ,
А.С. Федоров
Šе%!е2,че“*%е ,““лед%"=…,е C!%це““= “%!Kц,, "%д%!%д=
“%ед,…е…, м, м=г…, , м%д,-,ц,!%"=……/м, =2%м=м, Pd
– 259 –
А.Г. Сургутскова, Г.В. Бурмакина, В.В. Сурсякова,
А.И. Рубайло
o!,ме…е…,е ме2%д= "/“%*%.--е*2,"…%г% *=C,лл !…%г% .ле*2!%-%!еƒ=
дл м%…,2%!,…г= =…,%……%г% “%“2="= C!е“…%"%д…/.
.*%“,“2ем …= C!,ме!е !е*, e…,“е
– 266 –
Свидетельство о регистрации СМИ
ПИ № ФС77-28-726 от 29.06.2007 г.
С.И. Цыганова, И.В. Королькова, Г.В. Бондаренко,
Н.В. Чесноков, Б.Н. Кузнецов
t%!м,!%"=…,е "/“%*%C%!,“2/. 3гле!%д…/. м=2е!,=л%" ,ƒ
д!е"е“,…/ Kе!еƒ/, м%д,-,ц,!%"=……%L -%“-%!…%L *,“л%2%L ,
г,д!%*“,д%м *=л,
– 275 –
Стр.2
Journal of Siberian Federal University. Chemistry 3 (2009 2) 195-209
~ ~ ~
УДК 543.183.12
Sorption of Copper (II) from Aqueous Solutions on
Complexing Ion Exchangers and Determination of
Copper by Diffuse Refl ectance Spectroscopy
Olga N. Kononovaa
Sergey V. Kachina
b
and Alexander G. Kholmogorovb
a
*, Nataliya V. Fyodorovaa
Siberian Federal University,
79 Svobodny, Krasnoyarsk, 660041 Russia
Institute of Chemistry and Chemical Technology SB RAS,
42 K. Marx st., Krasnoyarsk, 660049 Russia 1
Received 3.08.2009, received in revised form 7.09.2009, accepted 14.09.2009
The present paper is devoted to sorption concentration of copper (II) from different solutions on
a number of complexing ion exchangers and subsequent determination of Cu (II) in a phase of
amphoteric ion exchanger AMF-2T of macroreticular structure by diffuse refl ectance spectroscopy.
The sorption properties of the sorbents were investigated. The apparent stability constants for copper
complexes in ion exchanger phase were calculated. The sorption-spectroscopic method is proposed
for Cu (II) determination in aqueous solutions. The calibration curve is linear at concentration range
0.05 – 3.0 mg/L (sample volume is 25.0 mL) and the detection limit is 0.03 μg/mL. The presence of Ni
(II), Co (II), Cr (III), Fe (II,III), Zn (II) as well as C2
O4
2–
and PO4
3–
(100-fold excesses) does not hinder
the determination of Cu (II).
Key words: copper, ion exchange, sorption, diffuse refl ectance spectroscopy.
Introduction
The production technologies
applied in
chemical industries often suppose the formation
of wash water and waste water with different
contents of heavy non-ferrous metals and
various salt compositions [1]. For example, the
hydrometallurgical production of chemical power
sources from manganese ores and concentrates
is based on complete purifi cation of manganese
salts from impurities of non-ferrous metals
(Cu2+
, Co2+
, Ni2+
not exceed 10-6
, Zn2+
), as their contents should
% [2-4]. The purifi cation of such
water from metal impurities can be carried out
* Corresponding author E-mail address: cm2@bk.ru
1
© Siberian Federal University. All rights reserved
# 195 #
by precipitation, electrochemical or ion exchange
and adsorption methods [5-9].
It is known that heavy metal ions act
harmfully on vital processes of men and animals,
coming into living organism together with
natural water. In view of that, the standards for
water quality are getting higher, and the contents
of heavy metal ions in waste and fresh water
are under a strict control [10,11]. The sorption
purifi cation of
one of
water [12,13] is considered
the most effective methods for water
purifi cation, as it allows water recycling after
the recovery of non-ferrous metal ions (Me2+
) by
,
Стр.3