Вестник МИТХТ, 2009, т. 4, № 6
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МИТХТ
6/2009
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Учредитель
МИТХТ им. М.В.Ломоносова
ТЕОРЕТИЧЕСКИЕ ОСНОВЫ ХИМИЧЕСКОЙ ТЕХНОЛОГИИ
Л.И. Матиенко, Л.А. Мосолова, Г.Е. Заиков.
Металлокомплексный катализ в окислительных процессах.
Кинетика и механизм
С.А. Решетов, А.К. Фролкова, А.А. Музыка. Влияние некоторых
структурных свойств ионных жидкостей на гомогенные и
гетерогенные свойства их смесей с водой и спиртами
А.Л. Таран, Н.В. Конохова, В.Е. Кучинский, Ю.А. Таран,
Д.С. Яковлев, Д.А. Кузина, И.П. Титова. Предложения по
реконструкции агрегатов производства аммиачной селитры под
производство пористой аммиачной селитры и аммиачной селитры
с наполнителями
В.М. Мясоеденков, Г.А. Носов, Е.М. Хайбулина. Влияние теплоотдачи
на эффективность разделения бинарных смесей при использовании
метода противоточной фракционной кристаллизации
ХИМИЯ И ТЕХНОЛОГИЯ ЛЕКАРСТВЕННЫХ ПРЕПАРАТОВ И
БИОЛОГИЧЕСКИ АКТИВНЫХ СОЕДИНЕНИЙ
Н.А. Брагина, Ю.Г. Кириллова, А.И. Лютик, А.Ф. Миронов,
В.И. Швец. Организация и методическое обеспечение
теоретического обучения аспирантов по специальностям
«Биоорганическая химия» и «Биотехнология»
Главный редактор:
проф. Тимофеев В.С.
Зам. главного редактора:
проф. Фролкова А.К.
проф. Фомичев В.В.
М.А. Грин, И.С. Лонин, Е.С. Ольшанская, А.Ф. Миронов. Синтез
гликоконъюгатов бактериохлорофилла а и лиганда галектинов на
основе производного -лактозиламина
Л.Ю. Гурьева, А.К. Большебородова, Ю.Л. Себякин. Синтез
углеводсодержащих компонентов липидных транспортных систем
направленного действия методом «click-chemistry»
Н.Н. Комова, Т.А. Никольская. Влияние магнитного поля на
седиментацию клеток, содержащих магнитные частицы
Редакционная коллегия:
доц. Биглов Р.Р.
проф. Дробот Д.В.
проф. Корнюшко В.Ф.
акад. РАН Кузнецов Н.Т.
акад. РАН Мирошников А.И.
проф. Мирошников Ю.П.
проф. Озерин А.Н.
проф. Серафимов Л.А.
проф. Сухорукова С.М.
проф. Тверской В.А.
акад. РАН Цивадзе А.Ю.
акад. РАМН Швец В.И.
доц. Юловская В.Д.
ХИМИЯ И ТЕХНОЛОГИЯ ОРГАНИЧЕСКИХ ВЕЩЕСТВ
С.П. Князев, А.Д. Кирилин, Е.А. Чернышев, П.А. Стороженко.
Исследование реакций «прямого синтеза» алкоксисиланов и
органоалкоксисиланов из кремния, спиртов и эфиров методами
квантовой химии
В.Ф. Третьяков, А.М. Илолов, Р.М. Талышинский, Н.А. Французова,
А.С. Попов. Термодинамический и кинетический анализ химического
сопряжения с реакцией дегидрирования метанола в формальдегид
ХИМИЯ И ТЕХНОЛОГИЯ НЕОРГАНИЧЕСКИХ МАТЕРИАЛОВ
А.А. Горшков, В.А. Ломовской, Е.К. Наими. О природе фона
внутреннего трения в поликристаллическом палладии.
К.А. Джусь, И.Г. Штатный, С.А. Григорьев. Наноструктурные
электрокатализаторы для водородного компрессора с твердым
полимерным электролитом
Г.М. Кузьмичева, А.А. Сатарова. Расчет границ изоморфной
смесимости в системе Ln3[M]2M3O12 – Ln3[Sc]2M3O12 (Ln = LaLu,Y;
M = Ga, Al)
И.Ю. Филатов, Н.А. Груздев, Ю.Н. Филатов. Влияние
полимерных добавок на процесс электроформования и структуру
нановолокнистых материалов
МАТЕМАТИЧЕСКИЕ МЕТОДЫ И ИНФОРМАЦИОННЫЕ
ТЕХНОЛОГИИ В ХИМИИ И ХИМИЧЕСКОЙ ТЕХНОЛОГИИ
Э.М. Карташов. Основные принципы термоупругости в
динамической постановке
М.И. Скворцова, Н.С. Рукк..Моделирование связи между
структурой и температурой плавления производных пиразолона:
топологический подход
© МИТХТ им. М.В. Ломоносова Abstracts
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СИНТЕЗ И ПЕРЕРАБОТКА ПОЛИМЕРОВ И КОМПОЗИТОВ НА ИХ ОСНОВЕ
М.Ю. Бокша, Ю.Н. Филатов, В.А. Козлов, Ю.А. Наумова.
Прогнозирование растворимости фторполимеров
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Вестник МИТХТ, 2009, т. 4, № 6
Review
MITHT
6/2009
Редакция:
Агаянц И.М.
Наумова Ю.А.
Семерня Л.Г.
Середина Г.Д.
CONTENTS
THEORETICAL BASED OF CHEMICAL TECHNOLOGY
L.I. Matienko, L.A. Mosolova, G.E. Zaikov. Metallocomplex
catalysis in oxidation processes. Kinetics and mechanisms
S.A. Reshetov, A.K. Frolkova, A.A. Muzyka. Influence of some
structural characteristics of the ionic liquids on homogeneous and
heterogeneous characteristics of their mixtures with water and alcohols
A.L. Taran, N.V. Konochova, V.E. Kuchinsky, Yu.A. Taran,
D.S. Yakovlev, D.A. Kuzina, I.P. Titova. Suggestions on converting
ammonium nitrate manufacturing capacity for production of porous
ammonium nitrates and ammonium nitrate with fillers
V.M. Myasoedenkov, G.A. Nosov, E.M. Khaibulina. The effect of heat
transfer on the efficiency of binary mixture separation in the method of
countercurrent fractional crystallization
Адрес редакции:
119571, г. Москва,
пр. Вернадского, 86,
к. Л-119
телефон: (495) 936-82-88
e-mail: vestnik@mitht.ru
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CHEMISTRY AND TECHNOLOGY OF MEDICAL PRODUCTS AND BIOLOGICALLY
ACTIVE SUBSTANCES
N.A. Bragina, J.G. Kirillova, A.I. Lutik, A.F. Mironov, V.I. Shvets.
The organization and methodical support of the theoretical education
of the graduate students specializing in the «Bioorganic chemistry»
and «Biotechnology»
52
M.A. Grin, I.S. Lonin, E.S. Ol’shanskaya, A.F. Mironov. Synthesis of
glycolconjugates of bacteriochlorophyll a and galectins ligand based
on β-lactosylamine derivative
L.Yu. Guryeva, A.К. Bolsheborodova, Y.L. Sebyakin. Synthesis of the
hydrocarbon components of the lipid transport systems using click-chemistry
N.N. Komova, T.A. Nikolskaya. Magnetic field influence on the
sedimentation of cells containing magnetic particles
Подписано в печать
20.12.2009 г. Формат 60x90/8.
Бумага офсетная.
Гарнитура Times.
Печать офсетная.
Уч. изд. листов 4,4.
Заказ № 572.
Тираж 500 экз.
CHEMISTRY AND TECHNOLOGY OF ORGANIC SUBSTANCES
S.P. Knyazev, A.D. Kirilin, E.A. Chernyshov, P.A. Storozhenko.
Investigation of the reaction of the Direct Synthesis of alkoxysilanes
and organoalkoxysilanes from silicon, alcohols and ethers by quantum
chemistry methods
V.F. Tretyakov, A.M. Ilolov, R.M. Talyshinsky, N.A. Frantsuzova,
A.S Popov. Thermodynamic and kinetic analysis of the chemical
reaction of methanol dehydration to formaldehyde
Отпечатано с оригинал-макета в
«ГЕЛИОПРИНТ»
119602, Москва, Ак. Анохина, 38, к. 1
CHEMISTRY AND TECHNOLOGY OF INORGANIC MATERIALS
A.A. Gorshkov, V.A. Lomovskoy, E.K. Naimi About the nature of the
background in the internal friction spectrum of polycrystalline
palladium
K.A. Dzhus, I.G. Shtatnii, S.A. Grigoriev. Nano-structured electrocatalysts
for hydrogen compressor with solid polymer electrolyte
G.M. Kuz’micheva, A.A. Sattarova. Calculation of the isomorfic
mixture limit in the system Ln3[M]2M3O12 – Ln3[Sc]2M3O12
(Ln = La-Lu,Y; M = Ga, Al)
SYNTHESIS AND PROCESSING OF POLYMERIC COMPOSITES
M.Y. Boksha, Y.N. Filatov, V. A. Kozlov, Y.A. Naumova. Predicting
solubility of fluoropolymers
I.Yu. Filatov, N.A. Gruzdev, Yu.N. Filatov. Influence of polymeric
additives on the process of electro casting and structure of nanofibrous
materials
INFORMATION TECHNOLOGIES AND APPLIED MATHEMATICS
E.M. Kartashov. Basic principals of thermoelasticity in dynamic
approximation
M.I. Skvortsova, N.S. Rukk. Modeling the relationship between the
structure and melting point of pyrazolone derivatives: topological
approach
Abstracts
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Вестник МИТХТ, 2009, т. 4, № 6
ABSTRACTS
L.I. Matienko, L.A. Mosolova, G.E. Zaikov. Metallocomplex catalysis in oxidation processes.
Kinetics and mechanisms.
Ways of increasing catalytic activity of complexes of transition metals towards oxidation of alkylarenes with
molecular oxygen, described in the literature within last 10-15 years, are reviewed. Attention is focused on
the original method of controlling the catalytic activity of complexes of M(acac)n (M=Ni(II), Fe(II,III), Co(II)) in
the oxidation reactions of alkylarene (e.g., ethylbenzene and cumol) to hydroperoxides by introducing the
mono- or polydentate electron-donating ligands L2
. Modeling of the catalytically active complexes of nickel as
selective catalysts for ethylbenzene oxidation to α-phenylethylhydroperoxide by introducing phenol (PhOH) in
the binary system {Ni(II)(acac)2+L2}, and also active complexes of nickel or iron by using quaternary
ammonium salts and macrocyclic polyethers as L2, is successfully realized by the authors. The role of Hbonding
in the mechanisms of the homogeneous catalysis is discussed. A strategy of controlling the catalytic
activity of Fe(II,III)(acac)n•L2 complexes (L2 =R4NBr or 18-crown-6 (18C6) by introducing small amounts of
H2O (~10-3 mol/l) is proposed. The activity of Ni and Fe catalysts in the processes of radical chain initiation
(O2 activation) and radical chain propagation (Catalyst + RO2• →) in the reactions of ethylbenzene oxidation
is discussed. The bibliography includes 144 references.
S.A. Reshetov, A.K. Frolkova, A.A. Muzyka. Influence of some structural characteristics of the
ionic liquids on homogeneous and heterogeneous characteristics of their mixtures with water and
alcohols.
The article presents a study of influence of the structural characteristics of ionic liquids, such as length of
alkyl chain of the cation, cation’s symmetry, type of the cation, type of the anion and some others, on the
homogeneous and heterogeneous characteristics of the mixtures of ionic liquids with water and alcohol.
A.L. Taran, N.V. Konochova, V.E. Kuchinsky, Yu.A. Taran, D.S. Yakovlev, D.A. Kuzina,
I.P. Titova. Suggestions on converting ammonium nitrate manufacturing capacity for production
of porous ammonium nitrates and ammonium nitrate with fillers.
The way of increasing competitiveness of the existing domestic factories manufacturing nitrogen containing
chemical fertilizers is suggested. The approach involves minimal retooling of the existing equipment which
will allow production of the ammonium nitrates containing fillers (e.g., manufacturing of ASN, CAN, AC, NP,
NK fertilizers) as well as manufacturing of porous ammonium nitrate (PAN).
V.M. Myasoedenkov, G.A. Nosov, E.M. Khaibulina. The effect of heat transfer on the efficiency of
binary mixture separation in the method of countercurrent fractional crystallization.
The analysis of heat transfer influence on the efficiency of separation in the countercurrent fractional
crystallization process was performed. Using a binary mixture as an example, it has been demonstrated that
considering the influence of heat transfer on the separation results in decrease of the height of zone of the
mass transfer in the countercurrent crystallization apparatus.
N.A. Bragina, J.G. Kirillova, A.I. Lutik, A.F. Mironov, V.I. Shvets. The organization and methodical
support of the theoretical education of the graduate students specializing in the «Bioorganic
chemistry» and «Biotechnology»
The organization and methodical support of the theoretical education of the graduate students specializing in
the «bioorganic chemistry» and «biotechnology» are presented. Experience accumulated upon teaching the
graduate students on the Department of Biotechnology and Department of Chemistry and Technology of
Biologically Active Compounds of Lomonosov State Academy of Fine Chemical Technology in 2006/2007
and 2007/2008 academic years is discussed.
M.A. Grin, I.S. Lonin, E.S. Ol’shanskaya, A.F. Mironov. Synthesis of glycolconjugates of bacteriochlorophyll
a and galectins ligand based on β-lactosylamine derivative.
Cycloimide bacteriochlorin p glycolconjugates with lactosylamine derivatives were obtained and their spectral
properties were investigated for the first time.
L.Yu. Guryeva, A.К. Bolsheborodova, Y.L. Sebyakin. Synthesis of the hydrocarbon components of
the lipid transport systems using click-chemistry
Neoglycolipids based on azide containing D-lactose derivative and di-esters of L-glutamic acid with terminal
acetylene group were synthesized by click-chemistry technology. Prepared compounds could be utilized in
targeted drug delivery systems.
N.N. Komova, T.A. Nikolskaya. Magnetic field influence on the sedimentation of cells containing
magnetic particles.
Magnetic field influence on the macrophage with the absorbed magnetic particles is investigated. It is
demonstrated that the application of magnetic field changes the speed of sedimentation of cells. Changes of
the nonsymmetrical indicatrix of the scattered light indicates that shape of the cells have changed under the
influence of the magnetic field.
S.P. Knyazev, A.D. Kirilin, E.A. Chernyshov, P.A. Storozhenko. Investigation of the reaction of the
Direct Synthesis of alkoxysilanes and organoalkoxysilanes from silicon, alcohols and ethers by
quantum chemistry methods.
The molecular and electronic structures and thermodynamic parameters of the reagents and the products of
the Direct Synthesis Reaction of alkoxysilanes and organoalkoxysilanes from silicon, alcohols and ethers
were calculated by the Hartree-Fock, DFT (including B3LYP/6-311+G**) and other methods of computational
chemistry.
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Вестник МИТХТ, 2009, т. 4, № 6
V.F. Tretyakov, A.M. Ilolov, R.M. Talyshinsky, N.A. Frantsuzova, A.S Popov. Thermodynamic and
kinetic analysis of the chemical reaction of methanol dehydration to formaldehyde.
Theoretical analysis of the possibility of conjugating the reaction of formaldehyde formation via
dehydrogenation of methanol with other initiating reactions is conducted; and advantages of using hydrogen
peroxide vs. organic inductors are discussed. When hydrogen peroxide is used, the reaction reaches
stationary condition almost immediately. It is demonstrated that the induction and the targeted reaction
proceed with high selectivity towards formaldehyde.
A.A. Gorshkov, V.A. Lomovskoy, E.K. Naimi. About the nature of the background in the internal
friction spectrum of polycrystalline palladium.
Analysis of the dissipation phenomena in the polycrystalline palladium in the range of temperatures from
120K to 800 K was conducted based on the spectrum of internal friction. It has been determined that set of
relaxation mechanisms and kinetic phenomena contribute to the background of the spectrum.
K.A. Dzhus, I.G. Shtatnii, S.A. Grigoriev. Nano-structured electrocatalysts for hydrogen compressor
with solid polymer electrolyte.
Highly effective, carbon supported nano-structured electrocatalysts for application in hydrogen compressor
with solid polymer electrolyte (PEM) are synthesized using a magnetron-ion dispersion method. New
membrane electrode assemblies (MEA) are developed, using the synthesized catalytic materials. The MEAs
allow for high specific characteristics of the hydrogen compressor. The developed electrocatalysts also can
find applications in the other systems such as fuel cells and water electrolyzers with PEMs.
G.M. Kuz’micheva, A.A. Sattarova. Calculation of the isomorfic mixture limit in the system
Ln3[M]2M3O12 – Ln3[Sc]2M3O12 (Ln = La-Lu,Y; M = Ga, Al).
The method of solid solution calculation in the system Ln3[М2]M3O12 - Ln3[ScyМ2-y]M3O12 (Ln = La-Lu, Y; М =
Ga, Al) has been developed. The theoretical model has been confirmed by experimental data.
M.Y. Boksha, Y.N. Filatov, V. A. Kozlov, Y.A. Naumova. Predicting solubility of fluoropolymers.
The article describes different approaches towards finding solubility parameter of fluorpolymers and also
provides comparative analysis of the obtained values.
I.Yu. Filatov, N.A. Gruzdev, Yu.N. Filatov. Influence of polymeric additives on the process of
electro casting and structure of nanofibrous materials.
The effect of addition of polymeric blends to spinning solution on fiber diameter and on structure of the
electrospun nanofibrous materials is investigated.
E.M. Kartashov. Basic principals of thermoelasticity in dynamic approximation.
The paper discusses basic principals of thermoelasticity, which derived from the key equations in dynamic
approximation.
M.I. Skvortsova, N.S. Rukk. Modeling the relationship between the structure and melting point of
pyrazolone derivatives: topological approach.
In the framework of the statistical approach the non-linear «structure – melting point» model for pyrazolone
derivatives is constructed. Number of topological parameters calculated from the structural formula was used
for the quantitative description of the molecular structure. The results of calculation of the melting points for a
series of compounds of considered class are reported.
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Вестник МИТХТ, 2009, т. 4, № 6
Вестник МИТХТ
Журнал выходит один раз в два месяца и публикует обзоры и статьи по
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2006 году. Учредителем журнала является Московская государственная академия
тонкой химической технологии им. М.В. Ломоносова (МИТХТ).
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химической технологии
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