5/2006 «Вестник МИТХТ»
Федеральное
агентство по образованию
Вестник
МИТХТ
Научно-технический
журнал
Издается
с февраля
2006 г.
Выходит один раз в
два месяца
Учредитель:
МИТХТ
им .М.В.Ломоносова
СОДЕРЖАНИЕ
СИНТЕЗ И ПЕРЕРАБОТКА ПОЛИМЕРОВ И КОМПОЗИТОВ НА ИХ ОСНОВЕ
5/2006 В.А. Шершнев, С.В. Емельянов. Реокинетические исследования
ISSN 1819-1487
формирования сетчатых структур в полимерах…………..……….... 3
октябрь Н.А. Булычев, И.А. Арутюнов, К. Айзенбах, В.П. Зубов. Модификация
дисперсных систем полимерами при механическом воздействии... 19
М.А. Гусева, О.Л. Грибкова, А.А. Исакова, В.Ф. Иванов, Ю.А.
Федотов, В.А. Тверской. Матричный синтез полианилина в присутствии
полимерной сульфокислоты.……………………………… 40
Д. А. Дрожжин, Л. Б. Кандырин, В. Н. Кулезнев, Н. Б. Урьев. Структура
и физико-механические свойства гибридных композиций на основе
ненасыщенной полиэфирной смолы и портландцемента……….. 44
Ю.П. Иощенко, Д.А. Кондруцкий, В.Ф. Каблов. Получение и
свойства полимолекулярных комплексов хитозана с биоразлагаемыми
полимерами……………………………………………………. 49
В.Я.Киселев, С.Ю. Кукушкин, Ю.И.Лякин, И.Н. Скворцов. Кремнеорганические
полмерные композиции медицинского назначения 54
Главный редактор:
В.С. Тимофеев
Зам. главного
редактора:
А.К. Фролкова
В.В. Фомичев
Редакционная
коллегия:
Р.Р. Биглов
Д.В. Дробот
В.Ф. Корнюшко
Н.Т. Кузнецов
А.И. Мирошников
Ю.П. Мирошников
А.Н. Озерин
Л.А. Серафимов
С.М. Сухорукова
В.А. Тверской
А.Ю. Цивадзе
В.И. Швец
В.Д. Юловская
© МИТХТ им. М.В. Ломоносова
Н.Н. Комова, Ю.В. Сыров, М.Д. Григорьев. Физическая природа
проводимости этилен-пропиленового сополимера, наполненного
хлоридом олова……………………………………………………….. 58
А.Е. Корнев, И.М. Агаянц, В.Г. Никольский, И.А. Красоткина,
Ю.А. Наумова, И.Б. Кравченко. Резины, содержащие тонкодисперсные
эластичные наполнители…………………………………… 63
А.Н. Матвиенко, Ю.П. Мирошников. Измерение межфазного натяжения
в расплавах смесей полимеров………………………… 68
Л.А. Меледина, Е.В.Сахарова, К.Л. Кандырин, Е.Э. Потапов. Исследование
взаимодействия компонентов в комбинированных
промоторах адгезии резины к латунированному металлокорду…... 74
ХИМИЯ И ТЕХНОЛОГИЯ ЛЕКАРСТВЕННЫХ ПРЕПАРАТОВ И БИОЛОГИЧЕСКИ
АКТИВНЫХ ВЕЩЕСТВ
Н.В. Иванова, С.И. Свиридов, А.Е. Степанов. Cинтез 2-(1,2,4триазол-3-ил)бензимидазольной
библиотеки……………………….. 78
В.С. Кублицкий, А.Е.Степанов, В.М. Трухан. Использование купратных
реагентов на основе хлорида меди (I) для синтеза транс-3замещенных
циклических -аминокислот………………………….. 82
ХИМИЯ И ТЕХНОЛОГИЯ НЕОРГАНИЧЕСКИХ ВЕЩЕСТВ
Ю.Г. Аляев, Ю.А. Ефимова, Г.М. Кузьмичева, И.Ю. Ловчиновский,
А.С. Ольшанская, Е.В.Философова, Л.М. Рапопорт, В.И. Руденко.
Методы исследования мочевых камней……………………... 86
Abstract……………………………………………………………....... 99
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5/2006 «Вестник МИТХТ»
Review
MITHT
5/2006
Редакция:
И.М. Агаянц
Ю.А. Наумова
Л.Г. Семерня
CONTENTS
Адрес редакции:
119571, г. Москва,
пр. Вернадского, 86,
к. Л-119
телефон: (495) 936-82-88
SYNTHESIS AND PROCESSING OF POLYMERIC COMPOSITES
V.A. Shershnev, S.V. Emeljanov. Rheokinetic investigations
of polymer networks formation………………………………. 3
N. Bulychev, I. Arutunov, C. Eisenbach, V. Zubov. Modification
of dispersed systems by polymers under mechanical
treatment…………………………………………………… 19
M.A.Guseva, O.L.Gribkova, A.A.Isakova, V.F.Ivanov,
Yu.A.Fedotov V.A.Tverskoy. Template synthesis of polyaniline
in presence of polymeric sulfoacid…………………… 40
D. A. Drozhzhin, L. B. Kandyrin, V. N. Kuleznev, N. B. Uriev.
Structure and physico-mechanical properties of hybrid compositions
based on unsaturated polyester resin and portlandcement… 44
V.F.Kablov, Y.P. Ioshchenko, D.A. Kondrutskij. Production
of the multimolecular complexes between chitosan and biodegradable
polymers and study of their properties…………....... 49
V.Y.Kiselev, S.J.Kukushkin, J.I.Lyakin, I.N.Skvorcov. The
application of silicon-based polymers in children stomatology 54
N.N.Komova, Yu.V.Sirov, M.D.Grigoriev. Physical character
conductivity of system, including ethylene-propylene copolymer
and SnCl2………………………………………….
58
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A.E. Kornev, I.M. Agayants, V.G.Nikolskii, I.A. Krasotkina,
J.A.Naumova, I.B. Kravchenko. The rubbers containing fine
elastic fillers…………………………………………………... 63
A.N. Matvienko, Yu.P. Miroshnikov. Measurement of interfacial
tension in melts of polymer blends………………………. 68
L.A.Meledina, E.V. Sakharova, K.L. Kandyrin, E.E. Potapov
The study of the components` interactions in the combined
brass-to-rubber adhesion promotors…………………………... 74
CHEMISTRY AND TECHNOLOGY OF MEDICAL PRODUCTS AND
BIOLOGICALLY-ACTIVE SUBSTANCES
N.V. Ivanova, S.I. Sviridov, A.E. Stepanov. Synthesis of
substituted
yl)benzimidazoles………………….
V. S. Kublitskii, A.E. Stepanov, V. M. Trukhan. The use of
copper reagents on the base of copper (I) chloride for the synthesis
of trans-3-substituted cyclic -amino acids……………. 82
CHEMISTRY AND TECHNOLOGY OF INORGANIC MATERIALS
Yu.Alyayev, Yu. Efimova, G.Kuz’micheva, E.Filosofova,
L.Rapoport, V.Rudenko. Experimental study of urinary stones 86
Abstract………………………………………………………. 99
2-(1,2,4-triazol-3- 78
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5/2006 «Вестник МИТХТ»
ABSTRACT
V.A. Shershnev, S.V. Emeljanov. Rheokinetic investigations of polymer networks
formation.
Methods of networks formation in different polymers or olygomers are considered. The possibility
of rheokinetic description for chemical network formation in elastomers and their
binary blends evaluation was shown. These elastomers differ from each other by polarity,
reactivity and crosslinking mechanisms. Rheokinetic method represents the new approach
for vulcanization regimes, structure and properties of such materials optimization
N. Bulychev, I. Arutunov, C. Eisenbach, V. Zubov. Modification of dispersed
systems by polymers under mechanical treatment
The processes of surface modification in aqueous dispersions of hydrophilic inorganic
pigments (titanium dioxide, ferrous oxide) as well as hydrophobic organic pigments (copper
phthalocyanine and carbon black) by polymers of various nature were reviewed. The
pigment surface modification by these polymers was achieved by conventional adsorption
as well as by mechanical (ultrasonic and vibrowave) treatment of the pigment dispersion.
The efficiency of the pigment surface coating was followed by the IR-analysis, Electrokinetic
Sonic Amplitude (ESA) method and transmission electronic microscopy that enabled
to gain quantitative data about the thickness and structure of polymer adsorption layers.
Ultrasonic and vibrowave techniques have been shown to provide significant improvement
of polymer adsorption layer thickness and to be a promising way for the surface
modification of pigments with regard to their dispersion stability. Thermo-responsive
(«smart») polymers were shown to be effective temperature-controlled modifiers for both
hydrophobic and hydrophilic pigments
M.A.Guseva, O.L.Gribkova, A.A.Isakova, V.F.Ivanov, Yu.A.Fedotov V.A.Tverskoy.
Template synthesis of polyaniline in presence of polymeric sulfoacid.
It was investigated the influence of the correlation of sulfoacid and aniline concentration
on the polymerization of the latter when it was protonated by polymeric sulfoacid
and on electronic structure of forming polyaniline.
D. A. Drozhzhin, L. B. Kandyrin, V. N. Kuleznev, N. B. Uriev. Structure and
physico-mechanical properties of hybrid compositions based on unsaturated
polyester resin and portlandcement.
Strength and deformation properties of cured compositions based on unsaturated
polyester resin and portlandcement were investigated in all range of concentrations.
Optimal ratio of components which lead to high strength properties and high deformation
ability was found
V.F.Kablov, Y.P. Ioshchenko, D.A. Kondrutskij. Production of the multimolecular
complexes between chitosan and biodegradable polymers and study of
their properties.
The multimolecular complexes were prepared from chitosan and biodegradable polymers.
Their mechanical and structural properties were studied; the thermodynamic
characteristics were calculated. It was shown that the films based on complexes
possess higher strength, sorbtial ability and flame resistance as compared to
the films from individual polymers
V.Y.Kiselev, S.J.Kukushkin, J.I.Lyakin, I.N.Skvorcov. The application of silicon-based
polymers in children stomatology
Our scientific research, concerned with the opportunities of the application of some new silicon-based
polymers at carrying out stomatologic procedures, is briefly submitted in this
article. The results of the comparative tests with the silicon-based polymeric materials and
the materials on the basis of the natural rubber are represented, as well as the graphic dependences
confirming legitimacy of made conclusions. At the end of the article, there is
the list of the scientific literature used as theoretical basis
99
3
19
40
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N.N.Komova, Yu.V.Sirov, M.D.Grigoriev. Physical character conductivity of
system, including ethylene-propylene copolymer and SnCl2.
Shown that conductivity of ethylene-polypropylene copolymer filled SnCl2 has ionic
character. The feasible mechanism of polymer electrolytes conductivity for system
ethylene-polypropylene copolymer – inorganic salt is considered according to experimental
data
A.E. Kornev, I.M. Agayants, V.G.Nikolskii, I.A. Krasotkina, J.A.Naumova,
I.B. Kravchenko. The rubbers containing fine elastic fillers
Influence elastic filler on properties of rubber mixes and vulcanizates is presented
A.N. Matvienko, Yu.P. Miroshnikov. Measurement of interfacial tension in
melts of polymer blends
The apparatus construction and primary techniques used on measurements of surface
and interfacial tensions in high-viscous polymer melts has been examined. This
method is based on spinning drop theory by Vonnegut. Measured values of surface
and interfacial tensions for several polymer systems show good correlation with
corresponding data from literature. Relative error of the measurements was in the
range of 2-8%
L.A.Meledina, E.V. Sakharova, K.L. Kandyrin, E.E. Potapov The study of the
components` interactions in the combined brass-to-rubber adhesion promotors.
Addition of active sulphur-containing component into promoter system along with
the use of silica as a substrate allowed us to reduce the amount of metal in rubber.
The adhesion improvement using «silica – metal salt – polysulfide» system is a result
of reciprocal activation of the system components. However, we found that polysulfide
adsorption on the silica surface is accompanied by chemical interaction
between the polysulfide molecules and surface reactive groups of silica. Hence, the
silica is not the inert substrate for the «polysulfide-metal salt» system
N.V. Ivanova, S.I. Sviridov, A.E. Stepanov. Synthesis of substituted 2-(1,2,4triazol-3-yl)benzimidazoles.
A
solution-phase synthesis for the preparation of substituted 2-(1,2,4-triazol-3yl)benzimidazoles
from triazole aldehydes and ortho-phenylenediamines has been
developed for the purpose of producing diverse lead generation libraries.
V.S. Kublitskii, A.E. Stepanov, V. M. Trukhan. The use of copper reagents
on the base of copper (I) chloride for the synthesis of trans-3-substituted
cyclic -amino acids.
An efficient synthesis of 3-substituted cyclic amino acids via 1,4-conjugate addition
of diorganocuprates to α,β-unsaturated cyclic α-aminoacids is described.The higher
reactivity of copper reagents obtained from copper (I) chloride in comparison with
CuCN, CuBr, CuI and CuBr*SMe2 has been shown
Yu.Alyayev, Yu. Efimova, G.Kuz’micheva, E.Filosofova, L.Rapoport,
V.Rudenko. Experimental study of urinary stones
Study of urinary stones of surgical removal has been fulfiled by complex methods.
Information of phase and element composition have been received, microstructural
examination has been made, causes of anomalous hardness of some stones have
been found.
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63
68
74
78
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