¹1(33) 2013
нанотехника
СОДЕРЖАНИЕ
Проблемы информации в области нанотехнологий и наноматериалов. Место России в мировом наносообществе.
Андриевский Ð.À., Ключарева Ñ.Â..................................................................3
О некоторых современных тенденциях в изучении свойств наноматериалов (обзор иностранной литературы).
Москвитин Ã.Â., Биргер Å.Ì., Поляков À.Í..........................................................14
Осамоорганизации наноразмерных частиц в процессах их агрегации. Жабрев Â.À., Марголин Â.È., Тупик Â.À. ............25
Физические основы атомно-молекулярной ñáîðêè. Потапов À.À.............................................32
Квантовая теория моделирования фемтосекундно-импульсной самосборки и самоорганизации активных
нанометровых частиц в материалах. Жуковский Ì.Ñ., Безносюк Ñ.À..........................................41
Карбоксилированные углеродные нанотрубки как активные компоненты сенсорных устройств.
Запороцкова È.Â., Поликарпова Í.Ï., Вилькеева Ä.Ý., Запороцков Ï.À. ......................................46
Исследование фото-, авто-электронной эмиссии в нанозернах антимонида и арсенида индия.
Жуков Í.Ä., Глуховской Å.Ã., Браташов Ä.Í.........................................................51
Температурные зависимости теплоемкости и теплопроводности эпоксидных материалов, модифицированных
металл/углеродными наноструктурами. Артанов А.М., Загребин Л.Д., Мухаметшина И.Ю.,
Кодолов Â.È., Чашкин Ì.À. ....................................................................57
Наномодифицированные гальванические ïîêðûòèÿ. Дьяков È.À.............................................60
Бактерицидная система «наночастицы серебра полипропиленовый волокнистый носитель»: получение и свойства.
Малиновская Ò.Ä., Лысак Ã.Â., Лысак È.À...........................................................69
Промышленные редкоземельные люминофоры для эффективных осветительных светодиодов.
Сощин Í.Ï., Личманова Â.Í., Большухин Â.À. .......................................................72
Исследование пористой структуры минерально-углеродных сорбентов для хроматографического разделения фуллеренов.
Постнов Â.Í., Крохина Î.À.....................................................................78
Исследование микроструктур наноразмерных солей нитратов, подвергшихся внешнему давлению.
Кузнецова È.À. .............................................................................81
Захват и передислокация порции воздуха управляемым потоком нанодисперсной магнитной жидкости.
Баштовой Â.Ã., Полунин Â.Ì., Боев Ì.Ë., Ряполов Ï.À. ................................................84
Многокластерная нанотехнологическая установка для исследования и изготовления наносхем
и функциональных наносистем для систем энергообеспечения космических аппаратов.
Дубовой À.Í., Родионов Á.Í., Егоров Ñ.Ä., Мазур Ñ.Í., Коротеев À.Â., Степанов Ì.Â., Хлюстов Ï.Ì.................91
Электрореологический эффект в полидиметилсилоксановой суспензии наноразмерного гибридного материала
диоксид титана-полипропиленгликоль. Агафонов À.Â., Краев À.Ñ., Давыдова Î.È., Захаров À.Ã......................105
Некоторые аспекты токсичности наночастиц серебра в эксперементе со взрослыми мышами
при пероральном приеме коллоидных растворов. Петрицкая Å.Í., Абаева Ë.Ô., Рогаткин Ä.À. .....................108
Взаимосвязь геометрических и электродинамических параметров фрактальных антенн. Бабичев Д.А., Тупик В.А. ..........113
НОВОСТИ .....................................................................116
ANNOTATION ..................................................................120
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¹1(33) 2013
NANOTECHNICS
TABLE OF CONTENTS
Problems of information in the field of nanotechnologies and nanomaterials. Place of Russia in the world nanocommunity.
Andriyevsky R.A., Klyucharyova S.V. ...............................................................3
On some modern tendencies of studying properties of nanomaterials (overview of foreign literature).
Moskvitin G.V., Birger E.M., Polyakov A.N...........................................................14
On self-organization of nanosized particles during their aggregation processes. Zhabrev V.A., Margolin V.I., Tupik V.A. .........25
Physical grounds of atomic and molecular assembly. Potapov A.A. .............................................32
Quantum theory of simulating femtosecond pulse self -assembly and self-organization
of active nanometer particles in materials. Zhukovsky M.S., Beznosiyuk S.A.......................................41
Carboxilized carbon nanotubes used as active components of sensor devices.
Zaporotskova I.V., Polikarpova N.P., Vilkeyeva D.E., Zaporotskov P.A. ......................................46
Studying photo-, autoelectronic emission in nanograins of indium antimonide and arsenide.
Zhukov N.D., Glukhovskoy Ye.G., Bratashov D.N.......................................................51
Temperature dependence of heat capacity and heat conductivity of epoxy matrerials modified with metal/carbon nanostructures.
Artanov A.M., Zagrebin L.D., Mukhametshina I.Yu., Kodolov V.I., Chashkin M.A. ................................57
Nanomodified galvanic coatings. Dyakov I.A. ..........................................................60
«Silver nanoparticles polypropylene fiberous carrier» bactericidal system: obtaining and properties.
Malinovskaya T.D., Lysak G.V., Lysak I.A. ..........................................................69
Industrial rare earth luminophores for effective enlightenment LEDs. Soshchin N.P., Lichmanova V.N., Bolshukhin V.A. ........72
Studying porous structure of mineral-carbon sorbents for chromatographic separtion of fullerenes. Postnov V.N., Krokhina O.A. ....78
Studying microstructures of nanosized salts of nytrates subjected to external pressure. Kuznetsova I.A. .....................81
Capturing and transfer of air portion by steered flow of nanodisperse magnetic fluid.
Bashtovoy V.G., Polunin V.M., Boyev M.L., Ryapolov P.A.................................................84
Multicluster nanotechnological setup for studying and manufacturing nanoschemes and functional nanosystems
for energy supply systems of spaceships. Dubovoy A.N., Rodionov B.N., Yegorov S.D.,
Mazur S.N., Koroteyev A.V., Stepanov M.V., Khlyustov P.M. ..............................................91
Electrorheological effect in polydimethyloxane suspension of titanium dioxide-polypropylenglycole nanosized hybrid material.
Agafonov A.V., Krayev A.S., Davydova O.I., Zakahrov A.G. ..............................................105
On influence of titanium dioxide nanoparticles upon internal organs of experimental animals at peroral introduction.
Petritskaya E.N., Rogatkin D.A., Abayeva L.F., Yeliseyev A.A., Gavrilov A.I....................................108
Mutual connection of geometrical and electromagnetic parameters of fractal antennas. Babichev D.A., Tupik V.A..............113
NEWS........................................................................116
ANNOTATION ..................................................................120
ISSN 1816-4498
АДРЕС РЕДАКЦИИ:
117246, ã. Ìîñêâà, Научный проезд 20, ñòð.4
Сдано в набор 18.03.2013. Подписано в печать 02.04.2013
Формат 60õ901/8 Бумага офсетная ¹1.
Ó÷.-èçä. ë. 15,5. Ôèç. ï. 15. Тираж 500. Заказ ¹ 189
ООО Издательство «Янус-К».
127411, Ìîñêâà, óë. Ó÷èíñêàÿ, ä.1
Отпечатано в ООО «Крайф»
127106, Ìîñêâà, óë.Áîòàíè÷åñêàÿ, ä.41, ï.7
Редакционный совет
Председатель:
Ананян Ì.À., ä.ò.í., ген.директор
Концерна «Наноиндустрия»
Члены совета:
Андриевский Ð.À., ä.ò.í., ïðîô., член совета РАН
по наноматериалам; Быков Â.Ï., ä.ô-ì.í., ïðîô.;
Сергеев Ã.Á., ä.õ.í., ïðîô.;
Цирлина Ã.À., ä.õ.í., ïðîô.;
Четверушкин Á.Í., ä.ô-ì.í., ÷ëåí-êîðð ÐÀÍ;
Левин À.Ñ., îòâ. cåêðåòàðü
Номер готовили:
Сапожников Ю.Т., Свидиненко Ю.Г.
Стр.2
Annotation
PROBLEMS OF INFORMATION IN THE FIELD OF NANOTECHNOLOGIES
AND NANOMATERIALS. PLACE OF RUSSIA IN THE WORLD NANOCOMMUNITY
Andriyevsky R.A., Klyucharyova S.V
The journals in the nanotechnology and nanomaterial field are analyzed. The significant increase of specialized journals
and papers in classic natural scientific journals is marked. The attention is taken to decrease of the Russian publication activity
in last years.
ON SOME MODERN TENDENCIES OF STUDYING PROPERTIES
OF NANOMATERIALS (OVERVIEW OF FOREIGN LITERATURE)
Moskvitin G.V., Birger E.M., Polyakov A.N.
The article provides an overview of the various experimental and analytical research methods of nanomaterials. The
work reflects World tendencies in this direction.
Are some of the leading firms engaged in research and application of nanomaterials. Shows some of the equipment that is
used to study the properties of nanomaterials.
Keywords: nanotechnology, nanomaterial, nanoparticle, nanouroven’, nanoindentor, nanocarapanie, nanosklerometr,
the test technique.
CARBOXILIZED CARBON NANOTUBES USED
AS ACTIVE COMPONENTS OF SENSOR DEVICES
Zaporotskova I.V., Polikarpova N.P., Vilkeyeva D.E., Zaporotskov P.A.
Volgograd state university, Volgograd, Russia, Universitetsky prospect, 100, 400062
Results of research of the mechanism of accession of carboxyl group to open border of a semi-infinite single-walled carbon
nanotube «zig-zag» for formation of chemically active sensor are presented. Interaction of the sensor with some alkaline
metals is studied. Process of scanning of any surface containing metal atoms or ions was modeled, and activity of functional
group –COOH to the chosen element was defined. Calculations were performed using the semi-empirical scheme
MNDO within the framework of the molecular cluster model and DFT method. The executed theoretical researches proved
possibility of creation of a highly sensitive sensor on the basis of the carboxylated carbon nanotubes.
Keywords: carboxylated carbon nanotube, sensory activity, functional carboxyl group, alkali metals, chemical active
probe, semi-empirical scheme MNDO.
STUDYING PHOTO-, AUTOELECTRONIC EMISSION IN NANOGRAINS
OF INDIUM ANTIMONIDE AND ARSENIDE
Zhukov N.D.1, Glukhovskoy Ye.G.2, Bratashov D.N.2
1"Volga-Svet" LLC, Saratov, Russia;
2Saratov State University, Saratov , Russia
Characteristics of field (autoelectronic) emission from nanograins of indium antimonide and arsenide narrow gap
semiconductors have been studied by tunneling microscopy method. Coulomb blockade and low field emission phenomena
have been detected and explained. Increased photo sensitivity has been noticed for own conductivity semiconductors. It
makes them prospective as regards using them as IR photo autocathodes.
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TEMPERATURE DEPENDENCE OF HEAT CAPACITY AND HEAT CONDUCTIVITY
OF EPOXY MATRERIALS MODIFIED WITH METAL/CARBON NANOSTRUCTURES
Artanov A.M.1, Zagrebin L.D.1, Mukhametshina I.Yu.1, Kodolov V.I.1,2,3, Chashkin M.A.3
1FGBOU VPO «The Izhevsk state technical university of a name of M.T.Kalashnikov«, Izhevsk, Russia
2Scientific and educational center of chemical physics and mezoskopiya
of UDNTs URO Russian Academy of Sciences, Izhevsk, Russia
3«Izhevsk Electromechanical Plant «Dome», Izhevsk, Russia
Using a dynamic, -calorimeter in the temperature range 298–373 K were measured and the results of changes in heat capacity
and thermal conductivity of epoxy resins modified with copper / carbon nanostructures. Found a change in thermal
and structural properties of modified copper/carbon nanocomposite epoxy polymers.
Keywords: epoxy resin, metal/carbon nanostructures, nanocomposite, specific heat, thermal conductivity.
NANOMODIFIED GALVANIC COATINGS
Dyakov I.A.
Tambov State Technical University, Tambov, Russia
The changes in the properties of the plating deposited in electrolytes containing carbon nanotubes. It is shown that the
use of carbon nanotubes CNM «TAUNIT» in electrochemical coatings alter morphology tribological properties and thermal
properties of coatings. Varying concentrations of CNM can control the properties of coatings, improving their properties.
Keywords: Electroplating, plating, nanomaterials, carbon nanotubes.
«SILVER NANOPARTICLES – POLYPROPYLENE FIBEROUS CARRIER»
BACTERICIDAL SYSTEM: OBTAINING AND PROPERTIES
Malinovskaya T.D., Lysak G.V., Lysak I.A.
The use of polypropylene fibrous material as a carrier for the silver nanoparticles was substantiated. By using of spectroscopic
methods the mechanisms of forming nanoparticles on the support surface in two-phasic activation by ultraviolet
and microwave radiations were investigated. The process of producing the bactericidal system of «silver nanoparticles – polypropylene
fibrous material» was developed. The created system demonstrates high bactericidal activity and could be used
for water cleaning from microbiological contamination.
Keywords: silver nanoparticles, polypropylene fibrous material, microwave radiation, bactericidal system.
INDUSTRIAL RARE EARTH LUMINOPHORES FOR EFFECTIVE ENLIGHTENMENT LEDS
Soshchin N.P., Lichmanova V.N., Bolshukhin V.A.
R&PC «Luminophor«, Fryazino, Russia
with structure bredigitå were prepared by use of the solid-state technology. For the synthesis were used nanodimension oxides:
YO
It was shown that the photoluminophores exhibit high quantum output to 96% and ensure the emission in LED in the
23 and fluoride salts.
white spectral region up to 145 lm/W.
Keywords: nanotechnologies, multiligand phosphors, structure garnet, LED, efficiency.
STUDYING POROUS STRUCTURE OF MINERAL-CARBON SORBENTS
FOR CHROMATOGRAPHIC SEPARTION OF FULLERENES
Postnov V.N., Krokhina O.A.
Saint-Petersburg State University Chemical Faculty, Saint-Petersburg, Russia
The parameters of the porous structure of the mineral-carbon sorbents (intended for the chromatographic separation of
theC60,C70 fullerenes) obtained by chemical vapour deposition and cyclic deposition of carbon, by means of the methods
of mercury porometry, low-temperature nitrogen adsorption, adsorption of benzene vapour were defined.
fullerenes in toluene in the gravity mode was determined.
It was found that the sorbents have complex porous structure and contain macropores, mesopores (3–6 nm), as well as
micropores.
It was shown that increasing the carbon content of mineral-carbon sorbents affects the pore size distribution.
A correlation between the volume of mesopores andC70 fullerene output in the process of chromatographic separation of
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The microcrystalline powders of photoluminophores for LED on the basis of aluminium garnets structure and silicates
23, Al O
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Annotation
STUDYING MICROSTRUCTURES OF NANOSIZED SALTS
OF NYTRATES SUBJECTED TO EXTERNAL PRESSURE
Kuznetsova I.A.
Moscow State University of Environmental Engineering, Russia
The paper presents the results of the research of microstructures of nanoscale salts nitrates, received in the result of seals
in the mould. Shows a comparison of nanoscale granules and the initial powders. The analysis of sealing materials.
Keywords: microstructure of nanomaterials, seal, microscopy, defects.
CAPTURING AND TRANSFER OF AIR PORTION BY STEERED FLOW
OF NANODISPERSE MAGNETIC FLUID
Bashtovoy V.G., Polunin V.M., Boyev M.L., Ryapolov P.A.
The processes of formation and relocation of an air cavity by the managed flow of nanodispersed magnetic fluid at a various
speed mode are discussed. In the approximation of «low-magnetic» environment by finding surfaces of a constant potential
of magnetostatic force, the shape of the cavity surface confined by magnetic levitation is studied. Experimental data
on the stability of the cavity at a time and its steadiness in relation to pressure from the non-uniform magnetic field are presented.
The results of evaluation of the size of bubbles detached from the cavity, received by two different methods, are in
adequate agreement with each other.
Key words: a magnetic fluid, a magnetic levitation, a magnetic field, an air cavity, a column of MF, air bubbles, a shape
of free surface.
MULTICLUSTER NANOTECHNOLOGICAL SETUP FOR STUDYING
AND MANUFACTURING NANOSCHEMES AND FUNCTIONAL NANOSYSTEMS
FOR ENERGY SUPPLY SYSTEMS OF SPACESHIPS.
Dubovoy A.N., Rodionov B.N., Yegorov S.D.,
Mazur S.N., Koroteyev A.V., Stepanov M.V., Khlyustov P.M.
Multi Cluster Nano Technology Complex (MCNTC) with the open architecture is described. Are shown structure and
opportunities of transport, technological, analytical modules MCNTC. In MCNTC group plasma technologies of clearing,
sedimentation, etching (PC, PECVD, PE, RIE, DLC) and nanolocal zond technologies nanoetching and nanodeposition
(NLZPE, NLZCVD) are realized. The modular open architecture, allows to provide flexible automatic control MCNTC
and to increase its transport, technological, analytical opportunities. Solving component MCNTC is module «Supercomputer».
It allows to organize closed a nanotechnology line – design-center + nanofabric. Module «Supercomputer» will allow
to model and project microstructures, nanoelements, nanocircuts, functional nanosystems, MEMS, NEMS which can be
made on MCNTC.
ELECTRORHEOLOGICAL EFFECT IN POLYDIMETHYLOXANE SUSPENSION OF TITANIUM
DIOXIDE-POLYPROPYLENGLYCOLE NANOSIZED HYBRID MATERIAL
Agafonov A.V., Krayev A.S., Davydova O.I., Zakahrov A.G.
G.A.Krestov Institute of Solution Chemistry of Russian Academy of Sciences, Ivanovo, Russia
Electrorheological effect in suspensions with nano-sized powders of inorganic-organic hybrid material titanium dioxide-poly(propylene)
glycol as filler was studied in polydimethylsiloxane. The content of the dispersed phase was 15 and 30
percent per volume. Description of apparatus for the measurement of electrorheological effect by the tensile stress-compression
electrorheological fluid in electric fields up to 5 kV/mm was given. 30 vol % suspension hybrid material titanium dioxide-poly(propylene)glycol
in the polydimethylsiloxane has a yield stress of 60 kPa in the electric field 4 kV/mm.
Keywords: electrorheological effect, electrorheological fluid, hybrid inorganic-organic nanomaterials, electric field influence.
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