Успехи химии
Том 92
Номер 9
2023
Содержание
N статьи
А.В.Иванов,
В.С.Щербакова,
Л.Н.Собенина
Г.И.Бородкин
M.Fu,
X.Lin,
X.Li,
Z.Tao
О.А.Залевская,
Я.А.Гурьева,
А.В.Кучин
RCR5090 Замещенные пирролы на основе кетонов:
перспективы использования и достижения
в синтезе
RCR5091 Механохимический синтез галогенорганических
соединений: взгляд синтетика
RCR5092 Применение микроволновой технологии
в области твердооксидных топливных
элементов
RCR5093 Комплексы палладия — перспективные
противомикробные препараты
i
Стр.2
Russian Chemical Reviews
Volume 92 Number 9 2023
Contents
Substituted pyrroles based on ketones: prospects of application and advances
in synthesis
A.V.Ivanov, V.S.Shcherbakova, L.N.Sobenina
A.E.Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Russia
This review considers the applications of pyrroles and compounds based on them in pharmaceutics and various
branches of technology in which pyrrole plays a key role. The emphasis is put on the studies that were not covered
in the previous reviews. The second part of the review summarizes the published data of the last 15 years on the
synthesis of pyrroles from widely used carbonyl compounds, which were chosen because of ready availability and
the possibility of varying the substituents. This type of systematization is proposed for the first time.
Bibliography — 199 references.
Mechanochemical synthesis of organohalogen compounds: a synthetic chemist’s view RCR5091
G.I.Borodkin
N.N.Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences,
Russia
Data on the mechanochemical synthesis of halogen-containing organic compounds published mainly over the past
10 years are summarized and critically analyzed. The established views about the methods of activation of
mechanochemical halogenation reactions are discussed. The mechanochemical fluorination, chlorination,
bromination and iodination reactions of organic compounds are considered. Particular attention is paid to reaction
mechanisms, selectivity problem and consideration of the mechanochemical method as a promising trend of green
chemistry. The review is devoted to applications of mechanochemistry in organic synthesis, while the fundamentals
of mechanochemistry are beyond the scope of the review.
Bibliography — 155 references.
Applications of microwave technology in the field of solid oxide fuel cell — a review RCR5092
M.Fu, X.Lin, X.Li, Z.Tao
a School of Resources, Environment and Safety Engineering, University of South China,
Hengyang, Hunan Province 421001, China
b Decommissioning Engineering Technology Research Center of Hunan Province Uranium Tailings Reservoir,
University of South China, Hengyang, 421001, PR China
Microwave heating has gained considerable attention as a promising technology for the processing of ceramics,
including materials used in solid oxide fuel cells (SOFCs). This unique heating method utilizes the dielectric loss of
materials in an electromagnetic field, offering advantages such as rapid heating rates and low energy consumption.
This review focuses on the recent applications and developments of microwave technology specifically for cathodes,
anodes, and electrolyte materials in SOFCs. A deeper understanding of the potential benefits and challenges
associated with microwave sintering can be gained by investigating the effects of microwave treatment on these
SOFC materials. The ultimate goal of the review is to provide valuable insights into microstructure control and
performance enhancement in SOFC materials through the use of microwave technology. By highlighting the
advances and discussing the underlying mechanisms, researchers and practitioners in the field can explore the
potential of microwave processing as a viable option for optimizing SOFC materials and improving overall cell
performance.
Bibliography — 106 references.
ii
RCR5090
Стр.3
Palladium complexes as promising antimicrobial agents
O.A.Zalevskaya, Ya.A.Gur’eva, A.V.Kutchin
RCR5093
Institute of Chemistry, Komi Scientific Centre, Ural Branch of the Russian Academy of Sciences, Syktyvkar, Russia
The review presents a summary and systematic analysis of the literature data on the antibacterial and antifungal
activity of palladium complexes with organic ligands published over the past three years. The structures of different
types of stable complexes are discussed. Taking into account the great structural diversity of the compounds under
consideration, the classification is performed in terms of the nature of donor centers of the initial ligands. A group
of palladium phthalocyanine complexes for photodynamic therapy is considered separately. The final section is
devoted to palladium complexes with terpene ligands, which are of scientific interest to the authors of this review.
Bibliography — 97 references.
iii
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