Журнал Сибирского федерального университета
Journal of Siberian Federal University
Химия
Chemistry
Редакционный совет
академик РАН Е.А.Ваганов
академик РАН И.И.Гительзон
академик РАН В.Ф.Шабанов
чл.-к. РАН, д-р физ.-мат.наук
А.Г.Дегерменджи
чл.-к. РАН, д-р физ.-мат. наук
В.Л.Миронов
чл.-к. РАН, д-р техн. наук
Г.Л.Пашков
чл.-к. РАН, д-р физ.-мат. наук
В.В.Шайдуров
чл.-к. РАН, д-р физ.-мат. наук
В.В. Зуев
Editorial Advisory Board
Chairman:
Eugene A. Vaganov
Members:
Josef J. Gitelzon
Vasily F. Shabanov
Andrey G. Degermendzhy
Valery L. Mironov
Gennady L. Pashkov
Vladimir V. Shaidurov
Vladimir V. Zuev
Editorial Board:
Editor-in-Chief:
Mikhail I. Gladyshev
Founding Editor:
Vladimir I. Kolmakov
Managing Editor:
Olga F. Alexandrova
Executive Editor for Chemistry:
Boris N. Kuznetsov
CONTENTS / СОДЕРЖАНИЕ
Alexandra S. Gribanova, Vladimir A. Kucherenko,
Tatyana G. Shendrik and Yuliya V. Tamarkina
Interaction of Hydrogen Peroxide with Nanoporous Material
Prepared by Alkaline Activation of the Brown Coal
– 111 –
Н.В. Гарынцева, И.Г. Судакова, Б.Н. Кузнецов
q"%L“2"= .…2е!%“%!Kе…2%", C%л3че……/. ,ƒ 3*“3“…%*,“л%2…/.
л,г…,…%" д!е"е“,…/ C,.2/, %“,…/ , Kе!еƒ/
– 121 –
А.Ф. Шиманский, М.Н. Васильева,
À.Ñ. Ñàìîéëî, Ê.Í. Фомина
h%……/L Cе!е…%“ , де-е*2…= “2!3*23!= " д"%L…%м %*“,де
",“м32=-ге!м=…, Bi12
GeO20-X
– 127 –
Я.Ю. Черных, С.Н.Верещагин
h““лед%"=…,е гел,е"%L C!%…,ц=ем%“2, 3ƒ*%L -!=*ц,,
це…%“-е! .…е!ге2,че“*,. ƒ%л
– 135 –
Í.Ã. Âíóêîâà, À.Ë. Колоненко,
Â.À. Ëîïàòèí, Ã.Í. Чурилов
q!="…е…,е “Cе*2!=ль…/. .=!=*2е!,“2,* Cл=ƒм/ =!г%…%"%г% ,
*“е…%…%"%г% д3г%"/. !=ƒ! д%" =2м%“-е!…%г% д="ле…,
– 148 –
Ë.Ò. Äåíèñîâà, Í.Â. Белоусова, Â.Ì. Äåíèñîâ,
Ñ.Ä. Êèðèê, Ã.Ì. Çååð, Ò.Â. Осипович
t%!м,!%"=…,е %*=л,…/ …= ›,д*,. “Cл="=. медь-%л%"%“",…ец
–
153 –
Редактор И.А. Вейсиг Корректор Т.Е. Бастрыгина
Компьютерная верстка Е.В. Гревцовой
Подписано в печать 17.06.2011 г. Формат 84х108/16. Усл. печ. л. 8,8.
Уч.-изд. л. 8,0. Бумага тип. Печать офсетная. Тираж 1000 экз. Заказ 4607.
Отпечатано в ПЦ БИК СФУ. 660041 Красноярск, пр. Свободный, 82a.
2011 4 (2)
Стр.1
Editorial board for Chemistry:
Nikolai V. Chesnokov
Lubov ’ K. Altunina
Natalia G. Bazarnova
Vasiliy A. Babkin
Vicente Cebolla
Viktor M. Denisov
Zinfer R. Ismagilov
Sergey V. Kachin
Sergey D. Kirik
Wolfgang Klose
Vladimir I. Kovalchuk
Vladimir A. Likholobov
Yuri L. Mikhlin
Gennady L. Pashkov
Anatoly I. Rubailo
Tatyana V. Ryazanova
Vladimir A. Sobyanin
Valeri E. Tarabanko
Tatyana G. Shendrik
Maxim L. Shchipko
Jean V. Weber
Â.Â. Ãîëîâèíà, À.Î. Åðåìèíà,
Н.В. Чесноков, Б.Н. Кузнецов
Šе.…%ге……%е "л, …,е %KAе*2%" Š}j …= д,…=м,*3 .,м,че“*,.
м,*!%.леме…2%" " "%де м=л%L !е*,
– 161 –
À.À. Ìèõååâ, Ã.Ì. Çååð, Î.Þ. Ôîìåíêî,
Ì.Þ. Кучинский, Ä.Ñ. Ðàéïîëüä, Î.Í. Ледяева
h““лед%"=…,е -,ƒ,*%-.,м,че“*,. C!%це““%" …= ме›-=ƒ…/.
г!=…,ц=. д,--3ƒ,%……/. “%ед,…е…,L 2,2=…%"/. “Cл="%" “
медью, 2=…2=л%м , ц,!*%…,ем
– 172 –
В.А. Шелехова, М.Б. Плотников, Е.А.Краснов
qCе*2!%-%2%ме2!,че“*%е %C!еделе…,е мед,K%!%л= " м=“л …/.
!=“2"%!=.
– 183 –
Ì.Þ. ×åðíÿê, Â.Å. Тарабанько, Â.À. Соколенко,
Â.È. Øàðûïîâ, À.À. Ìîðîçîâ, Å.Î. Сучкова
bƒ=,м%деL“2",е 5-K!%мме2,л-3!-3!%л= “ -2%!,д%м “е!еK!=
" ме2=…%ле , 2%л3%ле
– 191 –
Свидетельство о регистрации СМИ
ПИ № ФС77-28-726 от 29.06.2007 г.
Серия включена в «Перечень ведущих
рецензируемых научных журналов
и изданий, в которых должны
быть опубликованы основные научные
результаты диссертации на
соискание ученой степени доктора и
кандидата наук» (редакция 2010 г.)
А.С. Косицына, Н.А. Гаврилова,
Å.Ñ. Семиченко, Ã.À. Субоч
q,…2еƒ 4-…,2!%ƒ%- , 4-=м,…%C!%,ƒ"%д…/. N-=л*,л-3ме2,л=…,л,…%"
–
199 –
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Journal of Siberian Federal University. Chemistry 2 (2011 4) 111-120
~ ~ ~
УДК 661.183.2:66.094.37
Interaction of Hydrogen Peroxide
with Nanoporous Material Prepared
by Alkaline Activation of the Brown Coal
Alexandra S. Gribanova, Vladimir A. Kucherenko,
Tatyana G. Shendrik and Yuliya V. Tamarkina*
L.M. Litvinenko Institute of Physical-Organic
and Coal Chemistry, NAS of Ukraine
70 R. Luxemburg st., Donetsk, Ukraine 83114 1
Received 3.06.2011, received in revised form 10.06.2011, accepted 17.06.2011
The work analyzes applications of carbon adsorbents in catalytic wet peroxide oxidation (CWPO)
being a variant of Advanced Oxidation Processes (AOPs). Under CWPO condition (concentration
[Н2
О2
О2
to form ОН-radicals. This allows to combine two
] ≤ 30 %, 20±2 °C) we have studied the activity of nanoporous adsorbent АC-К prepared by
КОН-activation (800 °C, 1 h) of brown coal. We have compared АC-К with solid product of thermolysis
(SPT) of brown coal formed under the same conditions without КОН. АC-К, which has a high
adsorbtion activity, catalyzes decomposition of Н2
environmentally important processes: concentration of organic pollutants on the surface of adsorbent
and their further decomposition by ОН-radicals.
Decomposition of Н2
О2
(SPT) and grow under [Н2
О2
in presence of АC-К or SPT is described by kinetic fi rst-order equation and
runs 20-30 times faster in contact with АC-К. Rate constants vary within the range of 0.053-0.28 min-1
(АC-К) and 0.002-0.012 min-1
] increasing. Oxidative modifi cation of
АC-К and SPT surfaces under CWPO conditions has been studied. The dependence between content
of ОН groups in modifi ed АC-К (24 h) samples and [Н2
at [Н2
О2
О2
] is described as a curve with a maximum
] = 10 %, where the maximum modifying effect and the highest increse in ОН-groups content
(from 1.00 to 1.55 mmole/g) are observed. Modifi cation level is negligible; only 1 % of oxidant reacts
to form functional groups.
Keywords: nanoporous carbon, hydrogen peroxide, decomposition kinetics, surface modifi cation.
Research of Advanced Oxidation Processes (AOPs) is a relatively new and rapidly progressing
fi elds [1]. The beginning of AOPs was the discovery of radical oxidation of organic substances by
hydrogen peroxide in the presence of ferrum ions (Fenton’s reaction) [2]. Such processes are applied to
* Corresponding author E-mail address: y_tamarkina@rambler.ru
1
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